Selective molecular oxygen transport through a cellulose acetate membrane containing an electron-poor iron(II) porphyrin complexes

Abstract

Molecular oxygen diffusion in the cellulose acetate membranes containing the 5,10,15, 20-tetrakis(pentafluorophenyl)-21H,23H-porphine iron(II) was studied. Both the permeability coefficient and the separation factor for oxygen in the membrane containing the iron(II) porphyrin complex were increased with decreasing the upstream gas pressure which correspond to a dual-mode oxygen transport. The effects of the axial ligands of the iron(II) porphyrin on oxygen permeation was also examined in the same cellulose acetate membrane. The fluoride and 2-methyl imidazole ligands coordination to the iron(II) porphyrin induce to increase the oxygen permeability coefficient and the value of ideal separation factor.

This is a preview of subscription content, access via your institution.

References

  1. 1.

    Norman, H.:Inorganic. Chem.,25, 4714(1986).

    Article  Google Scholar 

  2. 2.

    Hernmingesn, E. and Scholander, P. F.:Science,132, 1379(1960).

    Article  Google Scholar 

  3. 3.

    Kemena, L. L., Noble, R. D. and Kemp, N.J.:J. Membrane Sci.,15, 259(1983).

    Article  CAS  Google Scholar 

  4. 4.

    Jonhson, B. M., Baker, R. W., Matson, S. L., Smith, K. L, Roman, I. C, Tuttle, M. E. and Lonsdale, H. K.:J. Membrane Sci,31, 31(1987).

    Article  Google Scholar 

  5. 5.

    Kawakami, H., Tsuda, K., Nishide, H. and Tsuchida, E.:Macromolecules,24, 3310(1991).

    Article  CAS  Google Scholar 

  6. 6.

    Nishide, H., Ohyanagi, M., Okada, O. and Tsuchida, E.:Macromolecules,19, 494 (1986).

    Article  CAS  Google Scholar 

  7. 7.

    Nishide, H., Ohyanagi, M., Okada, O. and Tsuchida, E.:Macromolecules,20, 417 (1987).

    Article  CAS  Google Scholar 

  8. 8.

    Ohyanagi, M., Nishide, H., Suenaga, K. and Tsuchida, E.:Macromolecules,21, 1590(1988).

    Article  CAS  Google Scholar 

  9. 9.

    Tsuchida, E., Nishide, H., Ohyanagi, M. and Okada, O.:J. Phys. Chem.,92, 6461 (1988).

    Article  CAS  Google Scholar 

  10. 10.

    Tschida, E., Hasegawa, E., Chika, Y., Babe, T. and Nishide, H.:Chem. Lett., 1727(1989).

  11. 11.

    Hasegawa, E., Fukuzumi, M., Nishide, H. and Tsuchida, E.:Chem. Lett., 123 (1990).

  12. 12.

    Cohen, I. A. and Caugey, W. S.:Biochemistry,7, 636 (1968).

    Article  CAS  Google Scholar 

  13. 13.

    Chang, C. K., Powell, D. and Traylor, T. G.:Croat. Chem. Acta.,49, 295 (1977).

    CAS  Google Scholar 

  14. 14.

    Chen, D.-G., Del Gaudio, J., La Mar, G. N. and Balch, A. L.:J. Am. Chem. Soc,99, 5486 (1977).

    Article  Google Scholar 

  15. 15.

    Almog, J., Baldwin, J. E. and Huff, J.:J. Am. Chem. Soc,97, 227 (1975).

    Article  CAS  Google Scholar 

  16. 16.

    Chang, C. K.:J. Am. Chem. Soc,99, 2819(1977).

    Article  CAS  Google Scholar 

  17. 17.

    Collman, J.P.:Acc Chem. Res.,10, 265(1977).

    Article  CAS  Google Scholar 

  18. 18.

    Collman, J. P., Gagne, R. R., Halbert, T. R., Marchen, J. C. and Reed, C. A.:J. Am. Chem. Soc,95, 7868 (1973).

    Article  CAS  Google Scholar 

  19. 19.

    Nishide, H., Ohyanagi, M. and Okada, O.:Macromolecules,19, 494(1986).

    Article  CAS  Google Scholar 

  20. 20.

    Nishide, H., Ohyanagi, M. and Tsuchida, E.:Macromolecules,20, 417(1987).

    Article  CAS  Google Scholar 

  21. 21.

    Ohyanagi, M., Nishide, H., Suenaga, K. and Tsuchida, E.:Macromolecules,21, 1950 (1988).

    Article  Google Scholar 

  22. 22.

    Nishide, H., Ohyanagi, M., Okada, O. and Tsuchida, E.:Macromolecules,21, 910(1980).

    Google Scholar 

  23. 23.

    Tsuchida, E., Nishide, H., Ohyanagi, M. and Okada, O.:J. Phys. Chem. 92, 6461 (1988).

    Article  CAS  Google Scholar 

  24. 24.

    Yu, B.-S. and Goff, H. M.:J. Am. Chem. Soc. 111, 6558 (1989).

    Article  CAS  Google Scholar 

  25. 25.

    Yu, B.-S.: Ph.D. Dissertation, University of Iowa, Iowa city (1989).

  26. 26.

    Perrin, D. D., Armarego, W. L. F. and Perrin, D. R.: “The Purification of Laboratory Chemicals” 2nd ed., Pergamon Press, New York (1980).

    Google Scholar 

  27. 27.

    Furniss, B. S., Hannaford, A. J., Rogers, V., Smith, P. W. G. and Tatchell, A. R.: “Vogel’s Textbook of Practical Organic Chemistry” 4th ed., The Chaucer Press, Ltd., Suffolk, p. 278 (1978).

    Google Scholar 

  28. 28.

    Eaton, S. S. and Eaton, G. R.:J. Am. Chem. Soc.,97, 3660 (1975).

    Article  CAS  Google Scholar 

  29. 29.

    Woon, T. C, Shirazi, A. and Bruice, T. C:Inorg. Chem.,25, 3845(1986).

    Article  CAS  Google Scholar 

  30. 30.

    Landrum, J. T., Atano, K., Scheidt, W. R. and Reed, C. A.:J. Am. Chem. Soc,102, 6729 (1980).

    Article  CAS  Google Scholar 

  31. 31.

    Brandrup, J. and Immergut, E. H.: “Polymer Handbook” 3rd ed., John Wiley & Sons, New York, VI 435(1989).

    Google Scholar 

  32. 32.

    Kawakami, H., Tsuda, K., Nishide, H. and Tsuchida, E.:Macromolecules,24, 3310(1991).

    Article  CAS  Google Scholar 

Download references

Author information

Affiliations

Authors

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Im, SW., Yu, BS. & Hong, SI. Selective molecular oxygen transport through a cellulose acetate membrane containing an electron-poor iron(II) porphyrin complexes. Korean J. Chem. Eng. 10, 207–210 (1993). https://doi.org/10.1007/BF02705269

Download citation

Keywords

  • Porphyrin
  • Permeability Coefficient
  • Oxygen Carrier
  • Cellulose Acetate Membrane
  • Oxygen Permeation