Abstract
A simple method is presented to obtain the Langmuir isotherm parameters. Although this method is limited to the case of large concentration, a few injections enable the determination of the parameters. For a sample of thymine, with the injection volumes of 1.0 and 1.5 ml, the parameters of a and b are determined as 15.83 ml/ml and 0.12 ml/mg, respectively.
Similar content being viewed by others
References
Eli Grushka (editor): “Preparative-Scale Chromatograph”, Marcel Dekker, Inc., New York (1989).
Ruthven, D.M.: “Principles of Adsorption and Adsorption Processes”, John Wiley & Sons, Inc., New York (1984).
Guiochon, G. and Ghodbane, S.:J. Phys. Chem.,92, 3682 (1988).
Ghodbane, S. and Guiochon, G.:J. Chromatogr.,450, 27 (1988).
Nogare, S.D. and Juvet, R.S.: “Gas-Liquid Chromatography: Theory and Practice”, John Wiley & Sons, Inc., New York (1962).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Row, K.H., Choi, DK. & Lee, Y.Y. Fast determination of Langmuir isotherm parameters in large concentration of one solute. Korean J. Chem. Eng. 7, 151–153 (1990). https://doi.org/10.1007/BF02705062
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02705062