Skip to main content
SpringerLink
Log in

Copper(II) complexes with aroylhydrazones

  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

The coordination chemistry of copper(II) with tridentate aroylhydrazones is briefly discussed in this article. Two types of aroylhydrazones derived from aroylhydrazines and ortho-hydroxy aldehydes or 2-pyridine-carboxaldehyde have been used. The characterization of the complexes has been performed with the help of various physico-chemical techniques. Solid state structural patterns have been established by X-ray crystallography. In the solid state, structural varieties of these complexes are seen to range from monomeric, dimeric, polymeric and one-dimensional self-assembly via hydrogen bonds and π-π interactions. EPR spectroscopy and variable temperature magnetic susceptibility measurements have been used to reveal the nature of the coordination geometry and magnetic characteristics of these complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hodgson D J 1975Prog. Inorg. Chem. 19 173

    Article  CAS  Google Scholar 

  2. Creutz C 1983Prog. Inorg. Chem. 30 1

    Article  CAS  Google Scholar 

  3. Kahn O 1985Angew. Chem., Int. Ed. Engl. 24 834

    Article  Google Scholar 

  4. Zanello P, Tamburini S, Vigato P A and Mazzocchin G A 1987Coord. Chem. Rev. 77 165

    Article  CAS  Google Scholar 

  5. Fenton D E 1983Advances in inorganic and bio-organic mechanisms (ed.) A G Sykes (London: Academic Press) vol. 2, p. 187

    Google Scholar 

  6. Fenton D E 1988Metal clusters in proteins (ed.) L Que Jr (Washington, DC: ACS)

    Google Scholar 

  7. Pal S N, Radhika K R and Pal S 2001Z. Anorg. Allg. Chem. 627 1631

    Article  CAS  Google Scholar 

  8. Sangeetha NR and Pal S 2000Bull. Chem. Soc. Jpn. 73 357

    Article  CAS  Google Scholar 

  9. Sangeetha N R and Pal S 1997J. Coord. Chem. 42 157

    Article  CAS  Google Scholar 

  10. Lakshmi A V, Sangeetha N R and Pal S 1997Indian J. Chem. A36 844

    Google Scholar 

  11. Sangeetha N R, Pal C K, Ghosh P and Pal S 1996J. Chem. Soc., Dalton Trans. 3293

  12. Sinn E 1976Inorg. Chem. 15 358

    Article  CAS  Google Scholar 

  13. Biradar N S and Havinale B R 1976Inorg. Chim. Acta 17 157

    Article  CAS  Google Scholar 

  14. IskanderMF,El-Aggan A M, Refaat L S and El Sayed L 1975Inorg. Chim. Acta 14 167

    Article  CAS  Google Scholar 

  15. Sangeetha N R, Baradi K, Gupta R, Pal C K, Manivannan V and Pal S 1999Polyhedron 18 1425

    Article  CAS  Google Scholar 

  16. O'Connor C J 1982Prog. Inorg. Chem. 29 203

    Article  Google Scholar 

  17. Mandal S K, Thompson L K, Newlands M J, Gabe E J and Nag K 1990Inorg. Chem. 29 1324

    Article  CAS  Google Scholar 

  18. Nag K 1990Proc. Indian Acad. Sci. (Chem. Sci.) 102 269

    CAS  Google Scholar 

  19. Hay P J, Thibeault J C and Hoffmann R 1975J. Am. Chem. Soc. 97 4884

    Article  CAS  Google Scholar 

  20. Sangeetha N R and Pal S 1999J. Chem. Crystallogr. 29 287

    Article  CAS  Google Scholar 

  21. StorhoffB N and Takats J 1977Coord. Chem. Rev. 23 1

    Article  Google Scholar 

  22. Beatti I R, Jones PJ, Howard JAK, Smart L E, Gilmore C J and Akitt J W 1979J. Chem. Soc., Dalton Trans. 528

  23. Bombieri G, Benetollo F, Klahne E and Fischer R D 1983J. Chem. Soc., Dalton Trans. 1115

  24. Blount J F, Freeman H C, Hemmerich P and Sigwart C 1969Acta Crystallogr. B25 1518

    Google Scholar 

  25. Gorter S and Veschoor G C 1976Acta Crystallogr. B32 1704

    CAS  Google Scholar 

  26. Chebolu V, Whittle R R and Sen A 1985Inorg. Chem. 24 3082

    Article  CAS  Google Scholar 

  27. Reinen D and Friebel C 1979Struct. Bonding 37 1

    CAS  Google Scholar 

  28. Hathaway B J 1984Struct. Bonding 57 55

    Article  CAS  Google Scholar 

  29. Hitchman M A, Maasicant W, van der Plas J, Simmons C J and Stratemeier H 1999J. Am. Chem. Soc. 121 1488

    Article  CAS  Google Scholar 

  30. Storrier GD, Colbran S B and Craig D C 1997J. Chem. Soc., Dalton Trans. 3011

  31. Folgado J V, Henke W, Allman R, Stratemeier H, Beltran-Porter D, Rojo T and Reinen D 1990Inorg. Chem. 29 2035

    Article  CAS  Google Scholar 

  32. Blake A J, Lavery A J and Schroder M 1996Acta Crystallogr. C52 37

    CAS  Google Scholar 

  33. Pal S N, Pushparaju J, Sangeetha N R and Pal S 2000Transition Met. Chem. 25 529

    Article  CAS  Google Scholar 

  34. Sangeetha N R and Pal S 2000Polyhedron 19 1593

    Article  CAS  Google Scholar 

  35. Chiari B, Helms J J, Piovesana O, Tarantelli T and Zanazzi P F 1986Inorg. Chem. 25 870

    Article  CAS  Google Scholar 

  36. Rojo T, Arriortua M I, Ruiz J, Darriet J, Villeneuve G and Beltran-Porter D 1987J. Chem. Soc., Dalton Trans. 285

  37. Marsh W E, Patel K C, Hatfield W E and Hodgson D J 1983Inorg. Chem. 22 511

    Article  CAS  Google Scholar 

  38. Estes W E, Hatfield W E, van Ooijen J A C and Reedijk J 1980J. Chem. Soc., DaltonTrans. 2121

  39. Sangeetha N R, Pal S N and Pal S 2000Polyhedron 19 2713

    Article  CAS  Google Scholar 

  40. Busch D H and Bailar J C Jr. 1956J. Am. Chem. Soc. 78 1137

    Article  CAS  Google Scholar 

  41. Harris C M and McKenzie E D 1962Nature (London) 196 670

    Article  CAS  Google Scholar 

  42. Menon M, Choudhury S, Pramanik A, Deb A K, Chandra S K, Bag N, Goswami S and Chakravorty A 1994J. Chem. Soc., Chem. Commun. 57

  43. Sangeetha N R, Pal S N, Anson C E, Powell A K and Pal S 2000Inorg. Chem. Commun. 3415

Download references

Author information

Authors and Affiliations

  1. School of Chemistry, University of Hyderabad, 500 046, Hyderabad, India

    Samudranil Pal

Authors
  1. Samudranil Pal
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pal, S. Copper(II) complexes with aroylhydrazones. J Chem Sci 114, 417–430 (2002). https://doi.org/10.1007/BF02703831

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02703831

Keywords

Search

Navigation