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Transition metal catalysed Grignard-like allylic activation across tetragonal tin(II) oxide

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Abstract

The reaction of allyl halide and a carbonyl compound under the aegis of tetragonal tin(II) oxide and catalyticd 8,d10 metal complexes provides the corresponding homoallylic alcohol, via a novel allyl tin intermediate.

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References

  1. Fenske D 1994 InClusters and colloids — from theory to applications (ed.) G Schmid (Weinheim: VCH)

    Google Scholar 

  2. Sinha P and Roy S 2001J. Chem. Soc., Chem. Commun. 1798;

  3. SinhaP, Kundu A, Roy S Prabhakar S, Vairamani M, Sankar A R and Kunwar A C 2001Organometallics 20 157;

    Article  Google Scholar 

  4. Kundu A and Roy S 2000Organometallics 19 105;

    Article  CAS  Google Scholar 

  5. Kundu A, Prabhakar S, Vairamani M and Roy S 1999Organometallics 18 2782;

    Article  CAS  Google Scholar 

  6. Kundu A, Prabhakar S, Vairamani M and Roy S 1997Organometallics 16 4796

    Article  CAS  Google Scholar 

  7. Barbier P 1898Comp. Rend. 128 110;

    Google Scholar 

  8. Grignard V 1900Comp. Rend. 130 322

    Google Scholar 

  9. Donaldson J D 1967Prog. Inorg. Chem. 8 287;

    Article  CAS  Google Scholar 

  10. Harrison P J 1989Chemistry of tin (New York: Blackie) pp 221;

    Google Scholar 

  11. Greenwood N N and Earnshaw A 1989Chemistry of the elements (Oxford: Pergamon Press)

    Google Scholar 

  12. Rousch W R 1991 InComprehensive organic synthesis (eds) B M Trost, I Fleming and C H Heathcock (Oxford: Pergamon Press) vol. 2, pp 1, and related chapters;

    Google Scholar 

  13. Marshall J A 1996Chem. Rev. 96 31;

    Article  CAS  Google Scholar 

  14. Thomas E J 1994Chemtracts-Org. Chem. 7 207;

    CAS  Google Scholar 

  15. Wakefield B J 1995Organomagnesium methods in organic chemistry (New York: Academic Press)

    Google Scholar 

  16. Ito A, Kishida M, Kurusu Y and Masuyama Y 2000J. Org. Chem. 65 494

    Article  CAS  Google Scholar 

  17. Maitilis P (ed.) 1971The organic chemistry of palladium (New York: Academic Press) vol. 1, 2

    Google Scholar 

  18. Brauer G (ed.) 1963Handbook of preparative inorganic chemistry (New York: Academic Press) vol. 1;

    Google Scholar 

  19. Brauer G (ed.) 1965Handbook of preparative inorganic chemistry (New York: Academic Press) vol. 2;

    Google Scholar 

  20. Brauer G and Itatori H 1965Inorg. Chem. 4 1618;

    Article  Google Scholar 

  21. Herrmann W A and Salzer A (eds) 1996Synthetic methods of organometallic and inorganic chemistry (New York: George Thieme Verlag) vol. 1 and 7

    Google Scholar 

Download references

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Authors and Affiliations

  1. Organometallics and Catalysis Laboratory, Chemistry Department, Indian Institute of Technology, 721 302, Kharagpur, India

    Pradipta Sinha, Moloy Banerjee, Abhijit Kundu & Sujit Roy

Authors
  1. Pradipta Sinha
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  2. Moloy Banerjee
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  3. Abhijit Kundu
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  4. Sujit Roy
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Correspondence to Sujit Roy.

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Sinha, P., Banerjee, M., Kundu, A. et al. Transition metal catalysed Grignard-like allylic activation across tetragonal tin(II) oxide. J Chem Sci 114, 277–283 (2002). https://doi.org/10.1007/BF02703820

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