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Synthesis and crystal structure of bis(di-n-butyldithiocarbamato)(1,10-phenanthroline)cadmium(II)

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Foundations of Physics Letters

Abstract

A new mixed-ligand complex, Cd(S2CN(C4H9)2)2Phen, is synthesized and investigated by thermal, element, and IR analyses and by diffractometry of polycrystals (DRON-3M, CuKα radiation, Ni filter). The crystal structure was determined on a CAD-4 Enraf-Nonius automatic diffractometer (MoKα radiation, θ from 1.5 to 25‡, 2325 nonzero independent reflections, 190 refined parameters, R = 0.036 for I > 2Σ(I)). Crystal data for C30H44CdN4S4 : a = 15.592(3), b = 22.724(5), c = 9.922(2) å, space group Pbcn, V = 3515.5(12) å3, Z = 4, M = 701.33, dcalc = 1.325 g/cm3. The structure involves monomeric molecules in which the cadmium atom has a distorted octahedral environment.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    A. V. Ivanchenko, S. A. Gromilov, S. M. Zemskova, I. A. Baidina & L. A. Glinskaya

Authors
  1. A. V. Ivanchenko
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  2. S. A. Gromilov
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  3. S. M. Zemskova
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  4. I. A. Baidina
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  5. L. A. Glinskaya
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Additional information

Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 4, pp. 682–687, July–August, 1998.

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Ivanchenko, A.V., Gromilov, S.A., Zemskova, S.M. et al. Synthesis and crystal structure of bis(di-n-butyldithiocarbamato)(1,10-phenanthroline)cadmium(II). Found Phys Lett 15, 554–558 (2002). https://doi.org/10.1007/BF02701386

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  • DOI: https://doi.org/10.1007/BF02701386

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