Skip to main content
SpringerLink
Log in

Crystal structure of platinum(II) chloro(1,1,1-trifluoro-4-imino-2-pentanononate(hydrate)) [PtC1(ktf)H2O]

  • Published:
Foundations of Physics Letters

Abstract

This paper reports on our study of the mixed-ligand Β-iminoketonate complex [PtCl(ktf)H2O] including l,l,l-trifluoro-4-imino-2-pentanone as a ligand. An X-ray diffraction analysis was performed on a CAD-4 diffractometer (MoKα radiation, Ω/2θ scan mode). Crystal data of PtClF3O2NC5H7: a =26.264(5), b =4.750(1), c =15.955(3) å, Β =108.16(3)‡, V = 1891.3å3, space group C2/c, Z = 8, dcalc = 2.82 g/cm3. The Pt atom has a distorted square planar environment. The Pt-Cl, Pt-O(H2O), Pt-N, and Pt-O bonds are 2.29, 2.07, 1.97, and 1.98 å in length, respectively. The chelate angle is 93.7‡. The environment of Pt is completed to pyramidal due to interactions with the Cα atom of the neighboring molecule at a distance of 3.57 å. The compound has a molecular structure. The molecules of the complex are stacked along the Y direction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. I. Zharkova, I. K. Igumenov, and S. V. Tkachev,Koordinats. Khim., 8, No. 1, 74–81 (1982).

    Google Scholar 

  2. S. Okeya, S. Oci, K. Matsumoto, et al.,Bull. Chem. Soc. Jpn., 54, 1085–1095 (1981).

    Article  Google Scholar 

  3. J. R. Hall and G. A. Swile,J. Organomet. Chem., 17, No. 1, 195–215 (1973).

    Article  Google Scholar 

  4. A. P. Gulya, S. G. Shova, G. V. Novitskii, et al.,Koordinats. Khim.,20, No. 2, 111–122 (1994).

    Google Scholar 

  5. F. A. Cotton, J. N. Francis, B. A. Frenz, et al.,J. Am. Chem. Soc.,95, No. 8, 2483–2486 (1973).

    Article  Google Scholar 

  6. S. Onuma, K. Horioka, H. Inoue, et al.,Bull. Chem. Soc. Jpn.,53, 2679–2680 (1980).

    Article  Google Scholar 

  7. I. A. Baidina, G. I. Zharkova, V. I. Alekseev, et al.,Zh. Strukt. Khim.,38, No. 3, 588–592 (1997).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    I. A. Baidina, G. I. Zharkova & S. A. Gromilov

Authors
  1. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. I. Zharkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 4, pp. 676–681, July–August, 1998.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baidina, I.A., Zharkova, G.I. & Gromilov, S.A. Crystal structure of platinum(II) chloro(1,1,1-trifluoro-4-imino-2-pentanononate(hydrate)) [PtC1(ktf)H2O]. Found Phys Lett 15, 549–553 (2002). https://doi.org/10.1007/BF02701385

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02701385

Keywords

Search

Navigation