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Molecular structure of tris(acetylacetonato)scandium Sc(C5H7O2)3

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Foundations of Physics Letters

Abstract

Molecular structure of tris(acetylacetonato)scandium, Sc(C5H7O2)3, is investigated by gas-phase electron diffractometry. The main structural parameters of the molecule are evaluated. The average intemuclear distances and angles correspond to C3 symmetry. The chief structural motif is trigonal antiprisms of six oxygen, carbon, and hydrogen atoms with a scandium atom at the center. It is found that rg[Sc-O) = 204.1(8) pm and rg(C−O) = 124.7(4) pm

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References

  1. V. A. Naumov and O. N. Kataeva,Molecular Structure of Organic Compounds of Oxygen and Sulfur in the Gas Phase [in Russian], Nauka, Moscow (1990), p. 103.

    Google Scholar 

  2. N. I. Giricheva, N. V. Belova, G. V. Girichev, et al.,Zh. Strukt. Khim., 33, No. 6, 76–83 (1992).

    Google Scholar 

  3. Yu. S. Ezhov, S. A. Komarov, V. G. Sevast’yanov, et al.,Vysokochist. VeshchesL, No. 1, 89–94 (1995).

  4. Yu. S. Ezhov, S. A. Komarov, V. G. Sevast’yanov, et al.,ibid., No. 5, 103–110 (1993).

  5. M. V. Popik, S. V. Sokolov, A. V. Golubinskii, et al., in:Structure and Properties of Molecules [in Russian], K. S. Krasnov (ed.), Ivanovo Chemical Technological Institute, Ivanovo (1988), pp. 84–93.

    Google Scholar 

  6. N. G. Rambidi and Yu. S. Ezhov,Zh. Strukt. Khim.,8, No. 1, 12–18 (1967).

    Google Scholar 

  7. M. V. Popik, M. A. Tafipolskii, S. Samdal, et al.,Kristallografiya,39, No. 2, 291–300 (1994).

    Google Scholar 

  8. R. A. Bonham and L. SchÄfer,International Tables of X-ray Crystallography, Kynoch Press, Birmingham (1974), p. 181.

    Google Scholar 

  9. V. P. Novikov and A. I. Malyshev,Zh. Prikl. Spektrosk., 33, No. 3, 545–549 (1980).

    ADS  Google Scholar 

  10. Yu. S. Ezhov, S. A. Komarov, and V. G. Sevast’yanov,Zh. Strukt. Khim.,39, No. 1, 46–54 (1998).

    Google Scholar 

  11. B. A. Kolesov and I. K. Igumenov,Spectrochim. Acta,40A, No. 3, 233–239 (1984).

    Article  ADS  Google Scholar 

  12. B. A. Kolesov and I. K. Igumenov,Koordinats. Khim.,11, No. 4, 485–489 (1985).

    Google Scholar 

  13. T. G. Anderson, M. A. Neuman, and G. A. Melson,Inorg. Chem.,12, No. 4, 927–930 (1973).

    Article  Google Scholar 

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Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 4, pp. 633–639, July–August, 1998.

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Ezhov, Y.S., Komarov, S.A. & Sevast’yanov, V.G. Molecular structure of tris(acetylacetonato)scandium Sc(C5H7O2)3 . Found Phys Lett 15, 514–519 (2002). https://doi.org/10.1007/BF02701381

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  • DOI: https://doi.org/10.1007/BF02701381

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