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Investigation of the structure and energetics of Β-diketonates. VIII. Molecular structure of the Ba(dpm)2 monomer according to gas phase electron diffraction data

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Abstract

A combined electron diffraction and mass spectrometric study of the overheated vapor over barium dipivaloylmethanate was performed. It was found that at 488°C the monomeric molecular form predominates in the vapor. The Ba(dpm)2 molecule has D2d symmetry. Its ra, rg, and rα parameters were determined.

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Authors and Affiliations

  1. Ivanovo State Chemical Engineering Academy, Ivanovo State University, Russia

    N. I. Giricheva, G. V. Girichev, N. V. Belova, N. A. Isakova, N. P. Kuzmina, A. R. Kaul & V. M. Petrov

  2. M. V. Lomonosov Moscow State University, Russia

    N. I. Giricheva, G. V. Girichev, N. V. Belova, N. A. Isakova, N. P. Kuzmina, A. R. Kaul & V. M. Petrov

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  1. N. I. Giricheva
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  2. G. V. Girichev
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  3. N. V. Belova
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  4. N. A. Isakova
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  5. N. P. Kuzmina
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  6. A. R. Kaul
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  7. V. M. Petrov
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Giricheva, N.I., Girichev, G.V., Belova, N.V. et al. Investigation of the structure and energetics of Β-diketonates. VIII. Molecular structure of the Ba(dpm)2 monomer according to gas phase electron diffraction data. J Struct Chem 40, 527–532 (1999). https://doi.org/10.1007/BF02700714

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  • DOI: https://doi.org/10.1007/BF02700714

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