Skip to main content
SpringerLink
Log in

Structure of the complex [trans-SnF4(H2O)2· (18-crown-6)· 2H2O]

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The molecular and crystal structure of the title complex (I) obtained by addition of tin fluoride in a hydrofluoric acid solution to 18-crown-6 in methanol was investigated by X-ray structure analysis. The crystals are monoclinic, space group P21/n, a = 13.497(3), b = 7.806(2), c = 9.892(2) Å, β = 95.57(3)°, Z = 2 for C12H32F4O10Sn. In the polymer chain, the crown ether molecules alternate with the inorganic complexes [trans-SnF4(H2O)2] and are linked to them by O-H...O type hydrogen bonds involving the intermediate water molecules. The weak C-H...F interactions bind the chains into the layers which are parallel to the xz plane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. F. Stoddart and R. Zarzycki,Cation Binding by Macrocycles, Y. Inoue and G. W. Gokel (eds.). Dekker, New York (1990), pp. 631–699.

    Google Scholar 

  2. S. J. Loeb,Comprehensive Supramolecular Chemistry, G. V. Gokel (ed.), Vol. 1, Pergamon (1966), pp. 733–753.

  3. R. H. Herber and A. E. Snelkinson,Inorg. Chem.,17, 1023–1029 (1978).

    Article  CAS  Google Scholar 

  4. R. H. Herber and G. Carrasquillo,ibid.,20, 3693–3697 (1981).

    Article  CAS  Google Scholar 

  5. E. N. Gur’yanova, L. A. Ganyushin, I. P. Romm, et al.,Zh. Obshch. Khim.,51, 437–442 (1981).

    CAS  Google Scholar 

  6. P. A. Cusack, B. N. Patel, and P. J. Smith,Inorg. Chim. Acta,76, L21-L23 (1983).

    Article  CAS  Google Scholar 

  7. P. J. Smith and B. N. Patel,J. Organomet. Chem.,243, 73–78 (1983).

    Article  Google Scholar 

  8. E. Hough, D. G. Nicholson, and A. K. Vasudevan.J. Chem. Soc., Dalton Trans. 2335–2337 (1986).

  9. G. Valle, A. Cassol, and U. Russo.Inorg. Chim. Acta. 82, 81–84 (1984).

    Article  CAS  Google Scholar 

  10. M. M. Amini, A. L. Rheingold. R. W. Taylor, and J. J. Zuckerman,J. Am. Chem. Soc.,106, 7289–7291 (1984).

    Article  CAS  Google Scholar 

  11. P. A. Cusack, B. N. Patel, P. J. Smith, et al.,J. Chem. Soc. Dalton Trans., 1239-1243 (1984).

  12. J. C. Barnes, H. A. Sampson, and T. J. R. Weakley,ibid. 949–953 (1980).

  13. A. Altomare, G. Cascarano, C. Giacovazzo, and A. Guagliardi.J. Appl. Crystallogr.,26, 343–353 (1993).

    Article  Google Scholar 

  14. G. M. Sheldrick,SHELXL-93. Program for Crystal Structure Refinement, University of Göttingen, Germany.

  15. V. O. Gelmboldt, éd. V. Ganin, Yu. A. Simonov, et al.,Koordinats. Khim.,21, No. 3, 183–190 (1995).

    Google Scholar 

  16. V. O. Gelmboldt, éd. V. Ganin, L. V. Ostapchuk, et al.,J. Incl. Phenom.,24, 287–299 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Physics, Academy of Sciences of Moldova Republic, Kishinev, Moldova

    M. S. Fonar’, Yu. A. Simonov, G. Bogelly, é. V. Ganin & V. O. Gelmboldt

  2. Center on Structure and Diffraction Research, Parma, Italy

    M. S. Fonar’, Yu. A. Simonov, G. Bogelly, é. V. Ganin & V. O. Gelmboldt

  3. Physicochemical Institute of Environmental and Human Control, Ministry of Education and Academy of Sciences of Ukraine, Odessa, Ukraine

    M. S. Fonar’, Yu. A. Simonov, G. Bogelly, é. V. Ganin & V. O. Gelmboldt

Authors
  1. M. S. Fonar’
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. Simonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Bogelly
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. é. V. Ganin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. O. Gelmboldt
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fonar’, M.S., Simonov, Y.A., Bogelly, G. et al. Structure of the complex [trans-SnF4(H2O)2· (18-crown-6)· 2H2O]. J Struct Chem 40, 926–930 (1999). https://doi.org/10.1007/BF02700701

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02700701

Keywords

Search

Navigation