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Structure and energetics of β-diketonates. IX. Molecular structure of Sr(DPM)2 according to gas phase electron diffraction data

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Abstract

Simultaneous electron diffraction and mass spectrometric investigation of overheated vapor of strontium dipivaloyl methanate was carned out. It was found that at 437(5)°C one molecular form, Sr(DPM)2, prevails in the vapor. The ra, rg, and rα structural parameters of the Sr(DPM)2 monomeric molecule were determined; the molecule was found to have D2d symmetry. The structural characteristics are compared in the series Ca(DPM)2—Sr(DPM)2—Ba(DPM)2.

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References

  1. N. I. Giricheva. N. A. Isakova. N. P. Kuzmina, et al.,Zh. Neorg. Khim.,41, No. 9, 1523–1530 (1996).

    CAS  Google Scholar 

  2. N. I. Giricheva, N. A. Isakova, G. V. Girichev, et al.,ibid.,41, No. 10, 1694–1696 (1996).

    CAS  Google Scholar 

  3. N. I. Giricheva, N. A. Isakova, G. V. Girichev, et al.,Zh. Strukt. Khim.,40, No. 3, 468–476 (1999).

    Google Scholar 

  4. N. I. Giricheva, G. V. Girichev, N. V. Belova, et al.,ibid.,40, No. 4, 647–653 (1999).

    Google Scholar 

  5. N. B. Morozova, G. I. Zharkova, P. A. Stabnikov, et al.,Synthesis and Physicochemical Studies of Alkaline Earth Β-Diketonates fin Russian], Novosibirsk (1989).

  6. S. B. Turnipseed, R. M. Barklay, and R. E. Sievers.J. Inorg. Chem.,30, 1164–1170(1991).

    Article  CAS  Google Scholar 

  7. A. S. Alikhanyan, I. P. Malkerova. N. P. Kuzmina. et al.,Zh. Neorg. Khim.,39, No. 9, 1534–1538 (1994).

    CAS  Google Scholar 

  8. G. V. Girichev, A. N. Utkin, and Yu. F. Revichev.Prib. Tekhn. éksp.,2, 187–190 (1984).

    Google Scholar 

  9. G. V. Girichev, S. A. Shlykov, and Yu. F. Revichev.ibid.,4, 167–169 (1986).

    Google Scholar 

  10. L. I. Ermolaeva, E. Z. Zasorin, and B. S. Bugaev, “Software for structural analysis of molecules by gas phase electron diffractometry. I. Program for primary treatment of experimental data,” Moscow State University, VINITI dep. No. 4203 (1979).

  11. R. Stolevik, H. M. Seip, and J. Cyvin,Chem. Phys. Lett.,15, No. 2, 263–265 (1972).

    Article  Google Scholar 

  12. W. D. Gwynn,J. Chem. Phys.,55, 477–481 (1971).

    Article  Google Scholar 

  13. B. Andersen, H. M. Seip, T. G. Strand, and R. Stolevik,Acta Chem. Scand.,23, 3224–3234 (1969).

    Article  CAS  Google Scholar 

  14. N. V. Belova, “Electron diffraction and mass spectrometric study of thermal stability and structure of some copper and yttrium Β-diketonates,” Chemical Sciences Candidate’s Dissertation, Ivanovo (1996).

  15. K. S. Krasnov (ed.),Molecular Constants of Inorganic Compounds [in Russian], Khimiya, Leningrad (1979).

    Google Scholar 

  16. J. T. Waber and D. T. Cromer,J. Chem. Phys.,42, No. 12, 4116–4123 (1965).

    Article  CAS  Google Scholar 

  17. A. Zabokrzycka, J. Brunvoll, et al.,J. Mol. Struct.,87, 141–154 (1982).

    Google Scholar 

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Authors and Affiliations

  1. Ivanovo State Chemical Engineering Academy, Ivanovo State University, Russia

    N. I. Giricheva, G. V. Girichev, N. V. Belova, N. A. Isakova & N. P. Kuzmina

  2. M. V. Lomonosov Moscow State University, Russia

    N. I. Giricheva, G. V. Girichev, N. V. Belova, N. A. Isakova & N. P. Kuzmina

Authors
  1. N. I. Giricheva
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  2. G. V. Girichev
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  3. N. V. Belova
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  4. N. A. Isakova
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  5. N. P. Kuzmina
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Giricheva, N.I., Girichev, G.V., Belova, N.V. et al. Structure and energetics of β-diketonates. IX. Molecular structure of Sr(DPM)2 according to gas phase electron diffraction data. J Struct Chem 40, 862–868 (1999). https://doi.org/10.1007/BF02700692

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  • DOI: https://doi.org/10.1007/BF02700692

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