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Statistical disordering of chalcogen atoms in the cluster fragments of K4[Re6(µ3-S)8-y (µ3-Te) y ,(CN)6]

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Abstract

An X-ray diffraction analysis was performed for three crystals K4[Re6(Μ3-S)8-y(Μ3-Te)y(CN)6], which are members of a continuous series of solid solutions obtained by high-temperature reactions using different substrates. The crystals are cubic, space group Ia3. Statistical disordering of chalcogen atoms in the [Re6(Μ3-S)8-y(Μ3-Te)y(CN)6] cluster fragments is examined using the data for the three crystals. The results of this analysis show that the extent of the statistical disordering of Te and S affects the crystal structure dimensions.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    N. V. Podberezskaya, A. V. Virovets, Yu. V. Mironov, L. P. Kozeeva, N. G. Naumov & V. E. Fedorov

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  1. N. V. Podberezskaya
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  2. A. V. Virovets
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  3. Yu. V. Mironov
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  4. L. P. Kozeeva
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  5. N. G. Naumov
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  6. V. E. Fedorov
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Podberezskaya, N.V., Virovets, A.V., Mironov, Y.V. et al. Statistical disordering of chalcogen atoms in the cluster fragments of K4[Re6(µ3-S)8-y (µ3-Te) y ,(CN)6]. J Struct Chem 40, 436–440 (1999). https://doi.org/10.1007/BF02700641

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  • DOI: https://doi.org/10.1007/BF02700641

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