Skip to main content
SpringerLink
Log in

Investigation of the structure and energetics ofΒ-diketonates. VI. Molecular structure of calcium dipivaloylmethanate Ca(DPM)2 according to gas phase electron diffraction data

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Combined mass spectrometric and electron diffraction study of the overheated vapor over calcium dipivaloylmethanate was performed. It was established that one molecular form, Ca(DPM)2, predominates in the vapor at 420–460‡C. The ra, rg and ra parameters of the Ca(DPM)2 molecule were determined, and the symmetry of the molecule was found to be D2d.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. V. Girichev, N. I. Giricheva, N. V. Belova, et al.,Zh. Neorg. Khim.,38, No. 4, 647–652 (1993).

    CAS  Google Scholar 

  2. G. V. Girichev, N. I. Giricheva, N. V. Belova, et al.,ibid.,38, No. 2, 342–345 (1993).

    CAS  Google Scholar 

  3. N. I. Giricheva, N. A. Isakova, N. P. Kuzmina, et al.,ibid.,41, No. 9, 1523–1530 (1996).

    CAS  Google Scholar 

  4. N. I. Giricheva, N. A. Isakova, N. P. Kuzmina, et al.,ibid.,41, No. 10, 1694–1696 (1996).

    CAS  Google Scholar 

  5. N. I. Giricheva, N. V. Belova, G. V. Girichev, et al.,Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol,35, No. 5, 51–68 (1992).

    CAS  Google Scholar 

  6. N. V. Belova, N. I. Giricheva, G. V. Girichev, et al.,Zh. Strukt. Khim.,38, No. 3, 470–488 (1997).

    Google Scholar 

  7. V. I. Sokolov, N. I. Giricheva, and G. V. Girichev,Abstracts of Papers from the Conference of Staff Members and Lecturers of Ivanovo State Chemical Engineering Academy, Ivanovo (1995), p. 38.

  8. N. B. Morozova, G. I. Zharkova, P. A. Stabnikov, et al., in:Synthesis and Physicochemical Studies of Alkaline Earth Β-Diketonates [in Russian], Novosibirsk (1989), p. 28.

  9. S. B. Turnipseed, R. M. Barklay, and R. E. Sievers,J. Inorg. Chem.,30, 1164–1170 (1991).

    Article  CAS  Google Scholar 

  10. A. S. Alikhanyan, I. P. Malkerova, N. P. Kuzmina, et al.,Zh. Neorg. Khim.,39, No. 9, 1534–1538 (1994).

    CAS  Google Scholar 

  11. N. A. Isakova, N. I. Giricheva, G. V. Girichev, et al.,Abstracts of Papers from the 9th International Conference of Young Scientists on Chemistry and Chemical Technology ‘ICCT-95’, Moscow (1995), p. 64.

  12. G. V. Girichev, S. A. Shlykov, and Yu. F. Revichev,Prib. Tekh. éksp., No. 4, 167–169 (1988).

  13. S. A. Shlykov and G. V. Girichev,ibid., No. 2, 141–142 (1988).

  14. L. I. Ermolaeva, E. Z. Zasorin, and B. S. Butaev, “Software for structural analysis of molecules by gas phase electron diffractometry. 1. Program for primary treatment of experimental data,” Moscow State University, VINITI dep. No. 4203 (1979).

  15. R. Stolevik, H. M. Seip, and J. Cyvin,Chem. Phys. Lett.,15, 263 (1972).

    Article  Google Scholar 

  16. W. D. Gwynn,J. Chem. Phys.,55, 477–481 (1971).

    Article  Google Scholar 

  17. B. Andersen, H. M. Seip, T. G. Strand, and R. Stolevik,Acta Chem. Scand.,23, 3224–3234 (1969).

    Article  CAS  Google Scholar 

  18. L. V. Vilkov, V. S. Mastryukov, and N. I. Sadova,Determination of the Geometrical Structure of Free Molecules, Mir, Moscow (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State Chemical Engineering Academy, Ivanovo State University, Russia

    N. I. Giricheva, N. A. Isakova, G. V. Girichev, V. M. Petrov & N. P. Kuzmina

  2. Ivanovo State Chemical Engineering Academy, Moscow State University, Russia

    N. I. Giricheva, N. A. Isakova, G. V. Girichev, V. M. Petrov & N. P. Kuzmina

Authors
  1. N. I. Giricheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Isakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Girichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. P. Kuzmina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giricheva, N.I., Isakova, N.A., Girichev, G.V. et al. Investigation of the structure and energetics ofΒ-diketonates. VI. Molecular structure of calcium dipivaloylmethanate Ca(DPM)2 according to gas phase electron diffraction data. J Struct Chem 40, 387–393 (1999). https://doi.org/10.1007/BF02700633

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02700633

Keywords

Search

Navigation