Skip to main content
Log in

Preexplosion phenomena in heavy metal azides

  • Published:
Combustion, Explosion and Shock Waves Aims and scope

Abstract

The paper reports results of investigation of the explosive decomposition of heavy metal azides in real time. The characteristics of the detected predetonation effects — the preexplosion conductance and luminescence of heavy metal azides — are described. The obtained value of the preexplosion conductivity of silver azide indicates that the process is of a chain nature. A model for the development of explosion of heavy metal azides is developed including multiplication of active particles (holes) by a first-order reaction and chain termination by a second-order reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. Bowden and A. Yoffe,Fast Reactions in Solids, Butterworth Sci. Publ., London (1958).

    Google Scholar 

  2. H. D. Fair and R. F. Walker (eds.),Energetic Materials. Plenum Press, New York (1987).

    Google Scholar 

  3. B. P. Aduev, É. D. Aluker, G. M. Belokurov, et al., “Examination of the mechanism of explosive decomposition of silver azide by high time resolution spectroscopy,”Izv. Vyssh. Uchebn. Zaved., Fiz.,39, No. 11, 162–175 (1996).

    Google Scholar 

  4. B. P. Aduev, E. D. Aluker, V. G. Kriger, and Yu. A. Zakharov, “Study of silver azide explosive decomposition by spectroscopic methods with temporal resolution,”Solid State Ionics,101–103, 33–36 (1997).

    Google Scholar 

  5. V. G. Kriger and A. V. Kalenskii, “Initiation of heavy metal azides by pulsed radiation,”Khim. Fiz., No. 4, 152–160 (1995).

    Google Scholar 

  6. V. I. Krasheninin, L. V. Kuz’mina, and V. Yu. Zakharov, “Physicochemical processes initiated by a constant electric field in filamentary crystals of silver azide,”Zh. Prikl. Khim.,69, No. 1, 21–24 (1996).

    Google Scholar 

  7. V. I. Krasheninin, L. V. Kuz’mina, V. Yu. Zakharov, and A. Yu Stalinin, “Decomposition of silver azide in an electric field: effect of transverse electric and magnetic fields,”Khim. Fiz.,14, No. 4, 126–135 (1995).

    Google Scholar 

  8. E. I. Aleksandrov and A. G. Voznyuk, “Effect of pulse duration on the sensitivity of lead azide to laser radiation,”Fiz. Goreniya Vzryva,19, No. 4, 143–146 (1983).

    Google Scholar 

  9. N. N. Semenov,Chain Reactions [in Russian], Nauka, Moscow (1986).

    Google Scholar 

  10. Yu. A. Zakharov, V. A. Nevostruev, S. M. Ryabykh, amd Yu. N. Safonov, “State of the art of the radiation chemistry of inorganic solids,”Khim. Vysok. Energ.,19, No. 5, 398–405 (1985).

    Google Scholar 

  11. É. D. Aluker, V. V. Gavrilov, R. G. Deich, and S. A. Chernov,Fast Radiation-Stimulated Processes in Alkali-Halide Crystals [in Russian], Zinante, Riga (1987).

    Google Scholar 

  12. S. I. Kurakin, G. M. Diamant, and V. M. Pugachev, “Morphology of silver azide crystals grown from ammonium oxyhydroxide,”Izv. Akad. Nauk SSSR, Neorg. Mat.,26, No. 11, 2301–2304 (1990).

    Google Scholar 

  13. B. P. Aduev, É. D. Aluker, G. M. Belokurov, and A. G. Krechetov, “Kinetics of explosive decomposition of silver azide by initiation by a laser pulse,”Khim. Fiz.,16, No. 8, 130–136 (1997).

    Google Scholar 

  14. B. P. Aduev, É. D. Aluker, and A. G. Krechetov, “Preexplosion luminescence of silver azide,”Khim. Fiz.,17, No. 3, 59–64 (1998).

    Google Scholar 

  15. A. B. Gordienko, Yu. N. Zhuravlev, and A. S. Poplavnoi, “Electronic structure of metal azides,”Phys. Status Solidi-B,198, 707–719 (1996).

    Article  Google Scholar 

  16. B. P. Aduev, É. D. Aluker, G. M. Belokurov, and A. G. Krechetov, “Preexplosion conductivity of silver azide,”Pis’ma Zh. Éksp. Teor. Fiz.,62, No. 3, 203–204 (1995).

    ADS  Google Scholar 

  17. F. Bassani and G. P. Parravicini,Electronic States and Optical Transitions in Solids, Pergamon Press, New York (1975).

    Google Scholar 

  18. O. V. Bogdankevich, V. S. Letokhov, and A. F. Suchkov, “Theory of the effects of inhomogeneous excitation of semiconductor lasers with electron beam pumping,”Fiz. Tekh. Poluprovod.,3, No. 5, 665–671 (1969).

    Google Scholar 

  19. É. D. Aluker, D. Yu. Lusis, and S. A. Chernov,Electron Excitations and Radioluminescence of Alkali-Halide Crystals [in Russian], Zinante, Riga, (1979).

    Google Scholar 

  20. B. P. Aduev, É. D. Aluker, A. G. Krechetov, and A. Yu. Mitrofanov, “Explosive luminescence of heavy metal azides,”Phys. Status Solidi-B,207, 535–540 (1998).

    Article  ADS  Google Scholar 

  21. B. P. Aduev, É. D. Aluker, Yu. A. Zakharov, et al., “Explosive luminescence of silver azide,”Pis’ma Zh. Éksp. Teor. Fiz.,66, No. 2, 101–103 (1997).

    ADS  Google Scholar 

  22. B. P. Aduev, É. D. Aluker, A. G. Krechetov, et al., “Spectrum of preexplosion luminescence of thallium azide,Pis’ma Zh. Éksp. Teor. Fiz.,25, No. 9, 28–31 (1999).

    Google Scholar 

  23. V. P. Gribkovskii,Theory of Light Absorption and Emission by Semiconductors [in Russian], Nauka Tekhnika, Minsk (1975).

    Google Scholar 

  24. B. P. Aduev, É. D. Aluker, A. G. Krechetov, and Yu. P. Sakharchuk, “Spectra of preexplosion optical absorption of silver azide,”Pis’ma Zh. Éksp. Teor. Fiz.,24, No. 16, 31–34 (1998).

    Google Scholar 

  25. J. Pankove,Optical Processes in Semiconductors, Englewood Cliffs, NJ (1971).

  26. E. H. Younk and A. B. Kunz, “An ab initio investigation of the electronic structure of lithium azide (LiN3), sodium azide (NaN3), and lead azide [Pb(N3)2],”Int. J. Quant. Chem.,63, No. 3, 615–621 (1997).

    Article  Google Scholar 

  27. P. A. Rodnyi, “Core-valence transitions in wide-band ionic crystals,”Fiz. Tverd. Tela,34, No. 7, 1975–1997 (1992).

    Google Scholar 

  28. B. P. Aduev, É. D. Aluker, V. V. Gavrilov, et al., “Optical effects in wide-gap materials due to band carriers,”Fiz. Tverd. Tela,38, No. 12, 3521–3530 (1996).

    Google Scholar 

  29. A. M. Stoneham,Theory of Defects in Solids, Clarendon Press, Oxford (1975).

    Google Scholar 

  30. M. S. Workentin, B. D. Wagner, F. Negri, et al. “Spectroscopic and theoretical studies of an unusual pseudohalogen radical anion,”J. Phys. Chem.,99, No. 1, 94–101 (1995).

    Article  Google Scholar 

  31. J. P. Spoonhower and A. P. Marchetti, “Trapped holes in silver halides,”J. Phys. Chem. Solids,51, No. 7, 793–804 (1990).

    Article  Google Scholar 

  32. S. Zeman, M. Dimin, S. Truchic, and V. Kabatova, “The relationship between the kinetic data of the low-temperature thermolysis and the heats of explosion of inorganic azides,”Thermochim. Acta.,80, 137–141 (1984).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated fromFizika Goreniya i Vzryva, Vol. 36, No. 5, pp. 78–89, September–October, 2000.

This work was supported by the Russian Foundation of Fundamental Research (Grant No. 98-03-32001a) and the Foundation of the Ministry of General and Professional Education of the Russian Federation.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aduev, B.P., Aluker, É.D., Belokurov, G.M. et al. Preexplosion phenomena in heavy metal azides. Combust Explos Shock Waves 36, 622–632 (2000). https://doi.org/10.1007/BF02699526

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02699526

Keywords

Navigation