Abstract
Ion-exchange membranes modified with sulfonic (-SO3H) and phosphonic acid (-PO3H) groups were prepared by radiation-induced grafting of glycidyl methacrylate (GMA) onto polyethylene (PE) films and sub-sequent sulfonation and phosphonation of poly(GMA) graft chains. The surface area, thickness and volume of grafted PE film increased with increasing grafting yield. The specific electrical resistance of PE membrane modified with the -PO3H and -SO3H groups decreased with increasing the ion-exchange capacity. The PE membrane modified with -PO3H group had a lower specific electrical resistance than that of PE membrane modified with -SO3H group.
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References
Chapiro, A., “Radiation Chemistry of Polymeric Systems,” Chap. 4, Interscience, New York (1962).
Choi, S. H., Nho, Y. C. and Kim, G. T., “Adsorption of Pb2+ and Pd2+ on Polyethylene Membrane with Amino Group Modified by Radiation-induced Graft CopolymerizationrJ. Appl. Polym. Sci.,71, 643 (1999).
Choi, S. H. and Nho, Y. C, “Adsorption of Co2+ and Cs1+ on Polyethylene Membrane with Iminodiacetic Acid and Sulfonic Acid Modified by Radiation-induced Graft Copolymerization,"J. Appl Polym. Sci.,71, 999(1999).
Choi, S. H. and Nho, Y. C, “Preparation and Electrical Properties of Polyethylene Membrane Modified with the Carboxylic Acid Group for Battery Separator,”Appl. Chem.,2(2), 652 (1998).
Choi, S. H. and Nho, Y. C, “Radiationinduced Graft Copolymerization of Mixture of Acrylic Acid and Acrylonitrile onto Polypropylene Film,”Kor. Polym. J.,6(4), 287 (1998).
Dworjanyn, P. A., Gamett, J. L., Jankiewicz, S. V. and Sangster, “Additive Effects in UV and Radiation Grafting and Curing Process of Value in Immobilization of Bioactive Materials,”IAEA-TECDOC-486,7 (1987).
Garnett, J. L., Kenyon, R. S., Levort, R., Long, M. A. and Yen N. T., “Acid Enhancement Effects in the Radiation Grafting of Monomers to Polyethylene and the Use of These Copolymers for Enzyme Immobilization and Related Reactions,”J. Macromol. Sci.-Chem.,A14(l), 87 (1980).
Garnett, J. L., Jankiewicz, S. V. and Sangster, D. R, “Mechanistic Aspects of the Acid and Salt Effect in Radiation Grafting,”Radiat. Phys. Chem.,36, 571 (1990).
Haddadai-Asl, L., Burford, R. P. and Garnett, J. L., “Radiation Graft Modification of Ethylene Rubber-II. Effect of Additives,”Radiat. Phys. Chem.,45(2), 191(1995).
Kakoi, T., Horinouchi, N., Goto, M. and Nakashio, F., “Selective Recovery of Palladium from Simulated Industrial Waste Water by Liquid Surfactant Membrane Process,”J. Membr. Sci.,118, 63 (1996).
Kim, M., Kiyohara, S., Konishi, S., Tsuneda, S., Saito, K. and Sugo, T., “Ringopening Reaction of Poly-GMA Chain Grafted onto Porous Membrane,”J. Membr. Sci.,117, 33 (1996).
Kiyohara, S., Sasaki, M., Saito, K., Sugita, K. and Sugo, T., “Amino Acid Addition to Epoxy-group-containing Polymer Chain Grafted onto a Porous Membrane,”J. Membr. Sci.,109, 87 (1996).
Kubota, N., Miura, S., Saito, K., Sugita, K., Watanabe, K. and Sugo, T., “Comparison of Protein Adsorption by Anion-exchange Interaction onto Porous Hollow-fiber Membrane and Gel Beadpacked Bed,”J. Membr. Sci.,117, 135(1996).
Moharram, M., Soliman, M. A. andEl-Gendy, H.M., “Electrical Conductivity of Poly(acrylic acid)-polyacrylamide Complexes,”J. Appl. Polym. Sci.,68, 2049 (1997).
Roboiras, M. D., “Electrochemical Properties of Cellulosic Ion-exchange Membranes II. Tansport Numbers of Ions and Electroosmotic Flow,”J. Membr. Sci.,109, 55(1996).
Saito, K., Kaga, T., Yamagishi, H., Furusaki, S., Sugo, T. and Okamoto, J., “Phosphorylated Hollow Fibers Synthesized by Radiation Grafting and Crosslinking,”J. Membr. Sci.,43, 131 (1989).
Tasaka, M., Kiyono, R., Kodaka, H., Niimi, Y. and Nagasawa, M., “Electrochemically Induced Chemomechanical Bending of Bilayered Ionexchange Membranes,”J. Membr. Sci.,126, 1, (1997).
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Choi, SH., Nho, Y.C. Electrochemical properties of polyethylene membrane modified with sulfonic and phosphonic acid groups. Korean J. Chem. Eng. 16, 725–730 (1999). https://doi.org/10.1007/BF02698343
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DOI: https://doi.org/10.1007/BF02698343