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One-fluid mixing rules for cubic equations of state: II. Solubility of solid mixtures in supercritical fluids

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Abstract

Three cubic equations of state are carefully examined to evaluate their capability for correlating the solubility of solid mixtures in supercritical fluids. After obtaining the pure solute-solvent interaction parameters, the solute-solute interaction parameters were directly calculated from the experimental ternary solubility data. The Redlich-Kwong, Soave, and Peng-Robinson equations of state correlate well the ternary data. However, the Redlich-Kwong equation of state gives the best result among them.

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References

  1. Lee, Y.Y., Kim H., Lee, H. and Hong, W.:Korean J. Chem. Eng.,5(1), 76(1987).

    Article  Google Scholar 

  2. Ziger, D.H. and Eckert, CA.:Ind. Eng. Chem. Process Des. Deo.. 22, 582 (1983).

    Article  CAS  Google Scholar 

  3. Allada, S.R.:Ind. Eng. Chem. Process Des. Dev.,23, 344(1984).

    Article  CAS  Google Scholar 

  4. Mart, C.J., Papadopoulos, K.D. and Donohue, M.D.:Ind. Eng. Chem. Process Des. Dev.,25, 394 (1986).

    Article  CAS  Google Scholar 

  5. Gilbert, S.W. and Eckert, CA.:Fluid Phase Equilibria,30, 41 (1986).

    Article  CAS  Google Scholar 

  6. Redlich, O. and Kwong, J.N.S.:Chem. Rev,44, 233(1949).

    Article  CAS  Google Scholar 

  7. Soave, G.:Chem. Eng. Sci.,27, 1197 (1972).

    Article  CAS  Google Scholar 

  8. Peng, D.Y.’and Robinson, D.B.:Ind. Eng. Chem. Fundam.. 15, 59(1976).

    Article  CAS  Google Scholar 

  9. Lydersen, A.L. : “Estimation of Critical Properties of Organic Compounds”, Univ. Wisconsin Coll. Eng., Eng. Exp. Stn. Rep. 3, Madison, Wl (1955).

  10. Tsekhanskaya, Y.V., Iomtev, MB. and Mushkina, E.V.:Russ. 1 Phys. Chem.,38, 1173 (1965).

    Google Scholar 

  11. Kurnik, R.T., Holla, S.J. and Reid, R.C.:J. Chem. Eng. Data,26, 47 (1981).

    Article  CAS  Google Scholar 

  12. Dobbs, J.M., Wong, J.M. and Johnston, K.P.:J. Chem. Eng. Dato,31, 303 (1986).

    Article  CAS  Google Scholar 

  13. Schmitt, W.J. and Reid, R.C.:J. Chem. Eng. Data,31, 204(1986).

    Article  CAS  Google Scholar 

  14. Kosal, E. and Holder, G.D.:J. Chem. Eng. Data,32, 148(1987).

    Article  CAS  Google Scholar 

  15. Pennisi, K.J. and Chimowitz, E.H.:J. Chem. Eng. Data,31, 285(1986).

    Article  CAS  Google Scholar 

  16. Kurnik, R.T. and Reid, R.C:Fluid Phase Equilibria,8, 93 (1982).

    Article  CAS  Google Scholar 

  17. Dobbs, J.M., Wong, J.M., Lahiere, R.J. and Johnston, K.P.:Ind. Eng. Chem. Res.. 26, 56 (1987).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Division of Chemical Engineering and Polymer Technology, Korea Advanced Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, Korea

    Youn Yong Lee, Hwayong Kim, Huen Lee & Won-Hi Hong

  2. Department of Chemical Engineering, Korea Institute of Technology, 400, Kusong-dong, Seo-gu, Taejon-shi, Chung-chong nam-do, Korea

    Huen Lee & Won-Hi Hong

Authors
  1. Youn Yong Lee
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  2. Hwayong Kim
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  3. Huen Lee
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  4. Won-Hi Hong
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Lee, Y.Y., Kim, H., Lee, H. et al. One-fluid mixing rules for cubic equations of state: II. Solubility of solid mixtures in supercritical fluids. Korean J. Chem. Eng. 5, 116–122 (1988). https://doi.org/10.1007/BF02697665

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  • DOI: https://doi.org/10.1007/BF02697665

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