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Regression of constrained parameters for nonlinear thermodynamic models

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Abstract

An algorithm based on variable Metric method has been applied to the determination of molecular thermodynamic model parameters from experimental data when any model need several constraints. Implementation of the method is illustrated in the reduction of multi-property equation of state data for the systems of argon, nitrogen and methane.

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References

  1. Powell, M.J.D.: “Variable Metric Methods for constrained optimization,” presented at the third International Symposium on computing Methods in Applied Sciences and Engineering, IR1A, France. (1977).

  2. Powell, M.J.D.: “A Fortran Subroutine for Constrained Optimization,” DAMTP; 82/NAA. (1982).

  3. Yoo, K.P.: Ph.D Dissertation. University Connecticut (1984).

  4. Rockafellar, R.J.: “Mathematical Programing,” vol. 5. pp. 354–373 (1973).

    Article  Google Scholar 

  5. Han, S.P.: “Mathematical Programing,” vol 11, pp. 263–282 (1976).

    Article  Google Scholar 

  6. Powell, M.J.D.: “A fast Algorithm for nonlinear constraints that use Lagrangian functions,” presented at the 9th International Symposium on Mathematical Programing, Budapest (1977).

  7. Dennis, J.E. and More, J.:SIAM Review, 19, 46(1977).

    Article  Google Scholar 

  8. Biggs, M.C.: “Constrained Minimization Using recursive Quatratic Programing”; in Towers Global optimization, eds. Dixon L.C.W. and Szego, G.P., North-Holland, Publishing Co., Amsterdam (1972).

    Google Scholar 

  9. Han, S.P.: A globally convergence method for nonlinear Programing. Report No. 75-257. Dept. of Computer Science, Cornell Univ. (1975).

  10. Carnahan, N.F., and Starling, K.E.:AlChE, 1, 18, 1184(1972).

    CAS  Google Scholar 

  11. Vera, J.H. and Prausnitz, J.M.:Chem. Eng. 1, 3, (1972).

    Google Scholar 

  12. Anderson, T.F. and Prausnitz, J.M.: 1 & EC. Proc. Des. & Dev. 19, 1(1980).

  13. Yoo, K.P. and Anderson T.F.:Ind. Eng. Chem. Fundam. 22., 177(1983).

    Article  CAS  Google Scholar 

  14. Din, F.: “Thermodynamic Functions of Gases,” Butterworths. London, vol 2–3 (1962).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Sogang University, Seoul, Korea

    Ki-Pung Yoo

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  1. Ki-Pung Yoo
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Yoo, KP. Regression of constrained parameters for nonlinear thermodynamic models. Korean J. Chem. Eng. 3, 77–81 (1986). https://doi.org/10.1007/BF02697527

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  • DOI: https://doi.org/10.1007/BF02697527

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