Skip to main content
Log in

Comparison of correlation equations for the prediction of gas chromatographic separation of alkylbenzenes

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

A detailed statistical analysis, comparing the validity of the best literature recommended equations for prediction of retention indices of alkylbenzenes on squalane and methylsilicone stationary phases with the unified retention index concept, is presented. A comparison with literature sources shows that the unified retention index provides the smallest residual error. Hence, it can be applied for prediction purposes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Loewenguth, D. Tourres, Fresenius’ Z. Anal. Chem.236, 170 (1968).

    Article  CAS  Google Scholar 

  2. L. Soják, A. Bučinská, J. Chromatogr.51, 75 (1970).

    Article  Google Scholar 

  3. N. Dimov, T. Petkova, D. Shopov, J. Chromatogr.74, 165 (1972).

    Article  CAS  Google Scholar 

  4. L. Soják, P. Majer, J. Krupčík, J. Janák, J. Chromatogr.65, 143 (1972).

    Article  Google Scholar 

  5. V. Pacáková, K. Koch, E. Smolková, Chromatographia6, 320 (1973).

    Article  Google Scholar 

  6. C. Döring, D. Estel, R. Fischer, J. Prakt. Chem.316, 1 (1974).

    Article  Google Scholar 

  7. G. Mitra, G. Mohan, A. Sinha, J. Chromatogr.91, 633 (1974).

    Article  CAS  Google Scholar 

  8. V. Švob, D. Deur-Šiftar, J. Chromatogr.91, 677 (1974).

    Article  Google Scholar 

  9. N. Dimov, T. Petkova, D. Shapov, J. Chromatogr.91, 691 (1974).

    Article  CAS  Google Scholar 

  10. J. Rijks, C. Cramers, Chromatographia7, 99 (1974).

    Article  CAS  Google Scholar 

  11. D. Papazova, M. Pankova, J. Chromatogr.105, 411 (1975).

    Article  CAS  Google Scholar 

  12. L. Soják, J. A. Rijks, J. Chromatogr.119, 505, (1976).

    Article  Google Scholar 

  13. W. Engewald, L. Wennrich, Chromatographia9, 540 (1976).

    Article  CAS  Google Scholar 

  14. L. Soják, J. Janák, J. A. Rijks, J. Chromatogr.135, 71 (1977).

    Article  Google Scholar 

  15. W. Engewald, L. Wennrich, E. Ritter, J. Chromatogr.174, 315 (1979).

    Article  CAS  Google Scholar 

  16. V. A. Gerasimenko, A. V. Kirilenko, V. M. Nabivach, J. Chromatogr.208, 9 (1981).

    Article  CAS  Google Scholar 

  17. N. Johansen, L. Ettre, Chromatographia15, 625 (1982).

    Article  CAS  Google Scholar 

  18. J. Macák, V. Nabivach, P. Buryan, S. Šinder, J. Chromatogr.234, 285 (1982).

    Article  Google Scholar 

  19. V. A. Gerasimenko, V. M. Nabivach, Zh. Anal. Khim.37, 110 (1982).

    CAS  Google Scholar 

  20. E. Kugucheva, V. Mashinskii, Zh. Anal. Khim.38, 2023 (1983).

    CAS  Google Scholar 

  21. T. Tóth, J. Chromatogr.279, 157 (1983).

    Article  Google Scholar 

  22. F. Vernon, B. Suratman, Chromatographia17, 600 (1983).

    Article  CAS  Google Scholar 

  23. J. A. Lubeck, D. L. Sutton, JHRC&CC,6, 328 (1983).

    Article  CAS  Google Scholar 

  24. B. Kumar, R. K. Kuchhal, P. Kumar, P. L. Gupta, J. Chromatogr. Sci.24, 99 (1986).

    Article  CAS  Google Scholar 

  25. S. Boneva, N. Dimov, Chromatographia,21, 697 (1986).

    Article  CAS  Google Scholar 

  26. E. Matisová, J. Chromatogr.438, 131 (1988).

    Article  Google Scholar 

  27. E. Matisová, M. Rukriglová, J. Krupčík, E. Kovačičová, S. Holotik, J. Chromatogr.455, 301, (1988).

    Article  Google Scholar 

  28. K. Héberger, Chromatographia25, 725 (1988).

    Article  Google Scholar 

  29. E. Matisová, E. Kovačičová, Pham Thi Ha, E. Kolek, W. Engewald, J. Chromatogr.475, 113 (1989).

    Article  Google Scholar 

  30. N. Dimov, Ov. Mekenyan, J. Chromatogr.471, 227 (1989).

    Article  CAS  Google Scholar 

  31. K. Héberger, Anal. Chim. Acta,223, 161 (1989).

    Article  Google Scholar 

  32. E. Matisová, P. Kurán, Chromatographia30, 328 (1990).

    Article  Google Scholar 

  33. B. D. Škrbić, J. Dj. Cvejanov, Chromatographia37, 215 (1993).

    Article  Google Scholar 

  34. B. D. Škrbić, M. B. Vojinović-Miloradov, Wat. Sci. Tech.30, 91 (1994).

    Google Scholar 

  35. L. S. Ettre, K. Billeb, J. Chromatogr.30, 1 (1967).

    Article  CAS  Google Scholar 

  36. L. S. Ettre, Chromatographia6, 489 (1973).

    Article  CAS  Google Scholar 

  37. N. Dimov, J. Chromatogr.347, 366 (1985).

    Article  CAS  Google Scholar 

  38. D. Papazova, N. Dimov, J. Chromatogr.356, 320 (1986).

    Article  CAS  Google Scholar 

  39. B. Škrbić, J. Cvejanov, Chromatographia34, 83 (1992).

    Article  Google Scholar 

  40. B. D. Škrbić, J. Dj. Cvejanov, Chromatographia35, 109 (1993).

    Article  Google Scholar 

  41. K. Héberger, Chromatographia29, 375 (1990).

    Article  Google Scholar 

  42. J. Bonastre, P. Grenier, Bull. Soc. Chim. Fr. 1395 (1967).

  43. D. Bonchev, Information Theoretic Indices for Characterization of Chemical Structures, Research Studies Press Chichester, 1983.

    Google Scholar 

  44. N. R. Draper, H. Smith, Applied Regression Analysis, John Wiley & Sons, New York, 1981.

    Google Scholar 

  45. Y. Bard, Nonlinear Parameter Estimation, Academic, New York, 1974, p. 269.

    Google Scholar 

  46. N. Dimov, P. Papazaova, Chromatographia,12, 720 (1979).

    Article  CAS  Google Scholar 

  47. N. Dimov, Ov. Mekenyan, Anal. Chim. Acta,212, 317 (1988).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Škrbić, B.D. Comparison of correlation equations for the prediction of gas chromatographic separation of alkylbenzenes. Chromatographia 41, 183–186 (1995). https://doi.org/10.1007/BF02688022

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02688022

Key Words

Navigation