Summary
α-Cyclodextrin dissolved in formamide solution was applied as the stationary phase in gas-liquid chromatography for the enantio- and diastereoselective separation of α-pinene and pinanes. It was found that the stereoselectivity arising from inclusion of these compounds in α-cyclodextrin cavities is considerable. The method developed was used to monitor the stereochemical cource of α-pinene hydrogenation.
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Kościelski, T., Sybilska, D., Belniak, S. et al. Gas-liquid chromatography system with α-cyclodextrin as an analytical tool for the studies of stereoselective hydrogenation of α-pinene. Chromatographia 19, 292–296 (1984). https://doi.org/10.1007/BF02687757
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DOI: https://doi.org/10.1007/BF02687757