Abstract
The theoretical factors in monotectic composite growth are reexamined. Perfect wetting of the solid by the monotectic liquid occurs whenever the monotectic temperature is close to the critical temperature. According to Chadwick, composite growth is impossible whenever such perfect wetting occurs. However, since the disjoining pressure is expected to be small, composite growth may instead be determined by the critical velocity necessary to overcome the disjoining pressure. Experience that high velocities are needed to form monotectic composites tends to support this alternate proposal. Applied pressure and ternary additions are suggested as additional ways for altering the factors that mediate composite growth.
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References
M. C. Flemings:Solidification Processing, Chpt. 4, McGraw Hill, N.Y., 1974.
R. J. Knight, C.-Y. Li, and C. W. Spencer:Trans. TMS-AIME, 1963, vol. 22, p. 18.
J. D. Livingston and H. E. Cline:Trans. TMS-AIME, 1969, vol. 245, p. 351.
F. D. Lemkey: U.S. Patent No. 3,434,827, March 25,1969.
G. A. Chadwick:Brit. J. Appl. Phys., 1965, vol. 16, p. 1095.
A. A. Chernov, D. E. Temkin, and A. M. Melnikova:Sov. Phys.-Crystallogr., 1976, vol. 21, p. 369.
A. D. Read and J. A. Kitchener:Wetting, p. 300, Society of Chemical Industry, Monograph No. 25, London, 1967.
J. W. Cahn:J. Chem. Phys., 1977, vol. 66, p. 3667.
R. B. Heady and J. W. Cahn:J. Chem. Phys., 1973, vol. 58, p. 896.
M. Moldover, R. Gammon, and J. W. Cahn: Unpublished research, NBS Washington, D.C., 1977.
C.S. Smith:Trans. ASM, 1953, vol. 45, p. 533.
M. Hansen, K. Anderko, R. P. Elliott, and F. A. Shunk:Constitution of Binary Alloys, 2nd ed. and Suppl., McGraw Hill, New York, 1958,1965, and 1969.
Y. Nakagawa:Acta Met., 1958,vol. 6, p. 704.
K. Iwasé, M. Okamoto, and T. Amemiya:Sci. Rep. Tohoku Univ., 1938, vol. 26, p. 618.
C.S Smith:J. Inst. Metals, 1934, vol. 54, p. 251.
J.W Cahn and R.J.Charles:Phys. Chem. Glasses, 1965,vol. 6,p. 181.
F. R. Mollard and M. C. Flemings:Trans. TMS-AIME, 1967, vol. 23, pp. 1526,1534.
J. T. MacQueen, F. R. Meeks, and O. K. Rice:J. Phys. Chem., 1962, vol. 66, p. 625.
O.K. Rice:J. Phys. Chem., 1976, vol. 64, p. 4362.
J. W. Cahn: ASM Symposium on Segregation, 1977, p. 3.
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Cahn, J.W. Monotectic composite growth. Metall Trans A 10, 119–121 (1979). https://doi.org/10.1007/BF02686415
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DOI: https://doi.org/10.1007/BF02686415