Skip to main content
SpringerLink
Log in

Crystal structure of the complex Zn(2,2′-Bipy)(C2H5OCS2)2 with mono- and bidentate ethylxanthate ligands

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

While seeking molecular precursors for ZnS films obtained by gas phase chemical deposition [1, 2] we synthesized mixed-ligand compounds ZnL(ROCS2)2 [R = i-Pr. /-Bu; L = 2,2′-bipyridyl (2,2′-Bipy), 1,10-phenanthroline (Phen)] [3]. The volatile complex Zn(2,2′-Bipy)(i-PrOCS2)2 was used as a precursor to obtain electroluminescent ZnS:Mn films [4]. According to XRD data, the compound Zn(Phen)(i-BuOCS2)2 is monomeric. The c.n. of zinc is six. The Phen and 1-B11OCS2 ions behave as cyclic bidentate ligands [3, 5]. It was assumed that other mixed-ligand complexes with Phen and 2,2′-Bipy have an analogous structure [3]. Here we report on the structure of the known mixed-ligand complex of zinc(II) ethylxanthate with 2,2′-bipyridyl [6, 7]. It was found that the behavior of alkylxanthate ligands in mixed-ligand complexes of zinc(II) is more complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. S. V. Larionov, Zh. Neorg. Khim., 38, No. 10, 1616–1624 (1993).

    Google Scholar 

  2. S. V. Larionov and S. M. Zemskova, Ross. Khim. Zh., 40, Nos. 4/5, 171–178 (1996).

    Google Scholar 

  3. T. G. Leonova, V. N. Kirichenko, L. A. Glinskaya, et al., Kootdinals. Khim., 23, No. 8, 590–595 (1997).

    Google Scholar 

  4. V. G. Bessergenev, V. I. Belyi, A. A. Rastorguev, et al., Thin Solid Films, 279, 135–139 (1996).

    Article  Google Scholar 

  5. L. A. Glinskaya, T. G. Leonova, V. N. Kirichenko, et al., Zh. Strukt. Khim., 38, No. 1, 142–147 (1997).

    Google Scholar 

  6. H. Krebs, E. F. Weber, and H. Fassbender, Z. Anorg. Chem., 276, Nos. 3/4, 128–134 (1954).

    CAS  Google Scholar 

  7. D. G. Holah and C. N. Murphy, Can. J. Chem., 49, No. 16, 2726–2732 (1971).

    Article  CAS  Google Scholar 

  8. G. M. Sheldrick, Ada Crystallogr., A46, 467–473 (1990).

    Article  CAS  Google Scholar 

  9. G. M. Sheldrick, ibid., A49 (Suppl.), C53 (1993).

    Article  Google Scholar 

  10. F. H. Allen, S. Bellard, M. D. Brice, et al., ibid., B35, 2331–2339 (1979).

    CAS  Google Scholar 

  11. C. L. Raston, A. H. White, and G. Winter, Austr. J. Chem., 29, 731–739 (1976).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USA

    L. A. Glinskaya, R. F. Klevtsova, T. G. Leonova & S. V. Larionov

Authors
  1. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. F. Klevtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. G. Leonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Larionov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zhumal Stmktumoi Khimii, Vol. 41, No. 1, pp. 196-201, January–February, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Glinskaya, L.A., Klevtsova, R.F., Leonova, T.G. et al. Crystal structure of the complex Zn(2,2′-Bipy)(C2H5OCS2)2 with mono- and bidentate ethylxanthate ligands. J Struct Chem 41, 161–165 (2000). https://doi.org/10.1007/BF02684743

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02684743

Keywords

Search

Navigation