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Electron diffraction study of the molecular structure of cesium metaborate

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Abstract

The molecular structure of cesium metabomte is studied by gas phase electrvn diffruction. The molecule has Cπ symmetry with mean intemuclear distances (Texp= 1080(10) K) Rg(Cs-O) = 269.2(15) pm, Rg(CS...B) = 360(6) pm, αgαg(CsOB) = 125(1)°. It is found that the deformation frequency V(CsOB) = 57(5) cm−1.

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Authors and Affiliations

  1. United Institute of High Temperatures. V. P. Glushko Thermal Center, Russian Academy of Sciences, USA

    Yu. S. Ezhov & S. A. Komarov

Authors
  1. Yu. S. Ezhov
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  2. S. A. Komarov
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Translated from Zhumal Struktumoi Khimii, Vol. 41, No. 1, pp. 67-73, 2000.

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Ezhov, Y.S., Komarov, S.A. Electron diffraction study of the molecular structure of cesium metaborate. J Struct Chem 41, 55–60 (2000). https://doi.org/10.1007/BF02684728

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  • DOI: https://doi.org/10.1007/BF02684728

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