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Synthesis and spectral-luminescent properties of poly(N-isopropylacrylamide)

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Abstract

The spectral-luminescent characteristics of water and methanol solutions of polymers containing tetraphenylporphyrin substituents were investigated. The water-soluble polymer was obtained by the interaction of poly(N-isopropylamide) containing N-oxysuccinimide substituents with 5-(4-aminophenyl)-10,15,20-triphenylporphyrin. From the synthesized polymer its analog with Zn-porphyrin substituents was obtained. This phenomenon is attributed to the specific features of the conformational behavior of polymeric chains in water solutions. Water solutions of polymers experience a thermally reversible phase transition upon heating, which is accompanied by a considerable enhancement of light scattering.

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Authors and Affiliations

  1. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., 220072, Minsk, Belarus

    Yu. S. Avlasevich, V. N. Knyukshto & K. N. Solov’ev

  2. Belarusian State University, Minsk, Belarus

    O. G. Kulinkovich

Authors
  1. Yu. S. Avlasevich
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  2. V. N. Knyukshto
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  3. O. G. Kulinkovich
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  4. K. N. Solov’ev
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Corresponding author

Correspondence to Yu. S. Avlasevich.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 483–487, July–August, 2000.

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Avlasevich, Y.S., Knyukshto, V.N., Kulinkovich, O.G. et al. Synthesis and spectral-luminescent properties of poly(N-isopropylacrylamide). J Appl Spectrosc 67, 663–669 (2000). https://doi.org/10.1007/BF02681301

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  • DOI: https://doi.org/10.1007/BF02681301

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