Skip to main content
Log in

X-ray luminescence of Pb-containing microcrystals dispersed in the CsCl Matrix

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

The process of complexing in CsCl crystals in activating them with lead haloids PbX2 (X=Cl, Br, I) (CPbX 2=1 mole %) is investigated. The formation of CsPbCl3 and Cs4PbCl6 microcrystals that are dispersed in the CsCl matrix is recorded. The luminescence-kinetic characteristics of the indicated microcrystals and single Pb2+v c centers are investigated. It is noted that the formation of the CsPbCl3 and Cs4PbCl6 microcrystals is hindered as the radius of the anion of the lead haloid PbX2 (X=Cl, Br, I) increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Barboza Flores, P. Fabeni, M. Gurioli, E. Mihokova, V. Nagirhyi, M. Nikl, G. P. Pazzi, R. Perez Salas, S. Zazubovich, and V. Zepelin, in: C. W. E. Van Eijk and P. Dorenbos (eds.),Inorganic Scintillators and Their Application. Proc. Int. Conf., Delft, the Netherlands, August 28 – Sept. 1, 1995; Delft University Press, Delft (1996), pp. 445–448.

    Google Scholar 

  2. M. Nikl, K. Nitsch, K. Polak, G. P. Pazzi, P. Fabeni, D. S. Citrin, and M. Gurioli,Phys. Rev. B,51, 5192–5199 (1995).

    Article  ADS  Google Scholar 

  3. S. V. Myagkota, A. S. Voloshinovskii, and V. B. Mikhailik, in:Int. Conf. on Inorganic Scintillators and Their Application, SCINT 97, September 22–25, 1997; Shanghai Institute of Ceramics, China (1997), p. 40.

    Google Scholar 

  4. V. V. Gavrilov, A. V. Gektin, N. V. Shiran, and T. A. Charkina,Opt. Spektrosk.,66, 961–964 (1989).

    Google Scholar 

  5. A. S. Voloshinovskii, V. B. Mikhailik, N. S. Pidzyrailo, P. A. Rodnyi, and A. Kh. Kkhudro,Zh. Prikl. Spektrosk.,56, 810–814 (1992).

    Google Scholar 

  6. E. N. Mel’chakov, P. A. Rodnyi, B. V. Rybakov, A. Ya. Smakov, and M. A. Terekhin,Opt. Spektrosk.,31, 276–279 (1989).

    Google Scholar 

  7. R. Aceves, V. Babin, M. Barboza Flores, P. Fabeni, E. Mihokova, V. Nagirhyi, M. Nikl, K. Nitsch, G. P. Pazzi, R. Perez Salas, and S. Zazubovich,J. Phys. Condens. Matter,10, 5449–5462 (1998).

    Article  ADS  Google Scholar 

  8. M. Nikl, E. Mihokova, and K. Nitsch,Solid State Commun.,84, 1089–1094 (1992).

    Article  Google Scholar 

  9. A. S. Voloshinovs’kii, V. B. Mikhailik, S. V. Myagkota, M. S. Pidzyrailo, and I. P. Pashuk,Ukr. Fiz. Zh.,38, 1012–1016 (1993).

    Google Scholar 

  10. M. Nikl, E. Mihokova, K. Nitsch, K. Polak, M. Rodova, M. Dusek, G. P. Pazzi, P. Fabeni, L. Salvini, and M. Gurioli,Chem. Phys. Lett.,220, 14–18 (1994).

    Article  ADS  Google Scholar 

  11. I. P. Antoniv, I. V. Garapin, and N. A. Tsal’,Izv. Akad. Nauk SSSR, Neorg. Mater.,24, 1749–1752 (1988).

    Google Scholar 

  12. D. W. Lynch,Phys. Rev.,118, 468–477 (1960).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. V. Myagkota.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 480–482, July–August, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Myagkota, S.V., Gloskovskii, A.V., Gaba, V.M. et al. X-ray luminescence of Pb-containing microcrystals dispersed in the CsCl Matrix. J Appl Spectrosc 67, 658–662 (2000). https://doi.org/10.1007/BF02681300

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02681300

Keywords

Navigation