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Low-frequency vibrational spectra of crystals of tutton salts

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Abstract

IR absorption spectra and polarized Raman spectra of crystals of Tutton salts K2M(SO4)26H2O and (NH4)2M(SO4)2·6H2O, where M=Co, Ni, Zn, have been obtained by experiment at 93 K and at room temperature. The frequencies and forms of normal modes of the [Zn(H2O)6]2+ octahedral complex have been calculated. The observed lines are assigned to the internal modes of the [M(H2O)6]2+ complex and external modes of the crystal lattice in accordance with the results of the calculations and factor-group analysis.

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Authors and Affiliations

  1. Belarusian State University, 4 F. Skorina Ave., 220050, Minsk, Belarus

    M. V. Barashkov, A. A. Zazhogin, A. I. Komyak & S. N. Shashkov

Authors
  1. M. V. Barashkov
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  2. A. A. Zazhogin
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  3. A. I. Komyak
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  4. S. N. Shashkov
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Corresponding author

Correspondence to M. V. Barashkov.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 445–449, July–August, 2000.

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Barashkov, M.V., Zazhogin, A.A., Komyak, A.I. et al. Low-frequency vibrational spectra of crystals of tutton salts. J Appl Spectrosc 67, 605–611 (2000). https://doi.org/10.1007/BF02681292

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  • DOI: https://doi.org/10.1007/BF02681292

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