Abstract
The optical density and luminescence ability of aqueous solutions of glutamine-tryptophan depend on the degree of oxidation of the initial dry substances of dipeptide. Glutamine-tryptophan has a high associating ability, which increases if stored. The general form of the optical absorption and luminescence spectra of the associates differs little from the spectra of monomers. Among the spectral-optical symptoms of association of a substance in a solution for glutamine-tryptophan, we discovered the hypochromism and narrowing of the absorption spectra and shortening of the fluorescence lifetime.
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References
Yu. S. Zuev, B. I. Kvasov, and V. L. Miroshnichenko,Methods of Spline Functions [in Russian], Moscow (1980).
G. Seber,Linear Regression Analysis, Moscow (1980).
A. S. Prishchepov and N. Nizamov,Zh. Prikl. Spektrosk.,43, 42–49 (1985).
A. S. Prishchepov, V. V. Nizhnikov, and G. P. Gurinovich,Zh. Prikl. Spektrosk.,33, 693–699 (1980).
J. Lakovich, in:Foundations of Fluorescence Spectroscopy [in Russian], Moscow (1986), pp. 345–351.
Temporary Pharmaceutical Articles 42-1981-90, 42-1982-90, and 42-1983-90.
A. S. Prishchepov and G. P. Gurinovich,Association of Chlorophyll and Pheophytin in a Mixture of Polar Solvents [in Russian], Preprint No. 161 of the Institute of Physics, Academy of Sciences of BSSR, Minsk (1978).
K. Jerassi, in:Dispersion of Optical Rotation, Moscow (1962), pp. 294–295.
K. Freudenberg and M. Meister,Lieb. Annal.,518, 86–89 (1935).
W. Kuhn, in:Stereochemistry, Leipzig (1932), pp. 412–415.
E. H. Strickland, C. Billups, and E. Kay,Biochemistry,11, 3657–3662 (1972).
A. A. Akhrem, T. D. Deshko, A. S. Prishchepov, O. A. Strel’chenok, and O. V. Sviridov,Bioorg. Khim.,5, 711–720 (1979).
A. S. Davydov, in:Theory of Molecular Excitons [in Russian], Moscow (1968), pp. 10–121.
A. S. Davydov, in:Theory of Light Absorption in Molecular Crystals [in Russian], Kiev (1951), pp. 21–67.
I. Tinoco,Red. Res.,20, 133–136 (1963).
I. Tinoco,Adv. Chem. Phys.,4, 113–118 (1962).
Short Chemical Encyclopedia [in Russian], Vol. 5, Moscow (1967), pp. 268–269.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 436–439, July–August, 2000.
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Prishchepov, A.S., Pil’ko, E.K. Optical spectra of aqueous solutions of glutamine-tryptophan associates. J Appl Spectrosc 67, 591–596 (2000). https://doi.org/10.1007/BF02681290
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DOI: https://doi.org/10.1007/BF02681290