Skip to main content
SpringerLink
Log in

Structural interpretation on the concentration dependence of molar volume in ternary aluminosilicate glasses containing oxides of the first and second groups of the periodic system

  • Science For Glass Production
  • Published:
Glass and Ceramics Aims and scope Submit manuscript

Abstract

The concentration dependence of the molar volume of ternary aluminosilicate glasses, in which the content of R2O (or RO) exceeds the Al2O3 content, is determined by the degree of depolymerization of the glass structural lattice. The molar volume in glasses with an equimolar content of R2O (or RO) and Al2O3 is additive and depends on the partial values of the molar volume of the “silica” and “aluminate” components in the structural lattice.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. I. Rabukhin, “Structural interpretation of concentration dependences of the molar volume of glasses in R2O — SiO2 and RO — SiO2 systems,”Steklo Keram., No. 11, 6–9 (1999).

  2. A. I. Rabukhin, “Structural interpretations of concentration dependences of the molar volume of glasses in R2O — R’2O — SiO2, RO — R’O — SiO2, and R2O — RO — SiO2 systems,”Steklo Keram., No. 12, 13–16 (1999).

  3. A. A. Appen,Chemistry of Glass [in Russian], Khimiya, Leningrad (1970).

    Google Scholar 

  4. G. Rowson,Inorganic Glass-Forming Systems [Russian translation], Mir, Moscow (1970).

    Google Scholar 

  5. G. B. Bokii,Chrystallochemistry [in Russian], Nauka, Moscow (1971).

    Google Scholar 

  6. O. V. Mazurin, M. V. Strel’tsina, and T. P. Shvaiko-Shvaikovskaya,Properties of Glasses and Glass-Forming Melts, A reference Book, Vol. 3, Part 1 [in Russian], Nauka, Leningrad (1977).

    Google Scholar 

  7. G. S. Karapetyan, V. Ya. Livshits, and D. G. Tennison, “Studies of elastic properties of lithium-aluminum glasses,”Fiz. Khim. Stekla,5(5), 314–319 (1979).

    CAS  Google Scholar 

  8. G. S. Karapetyan, V. Ya. Livshits, D. G. Tennison, and O. V. Zhukovskaya, “A study of elastic properties of lithium-aluminosilicate glasses with TiO2 additives and with Li2O/Al2O3>1,”Fiz. Khim. Stekla,6(4), 469–476 (1980).

    CAS  Google Scholar 

  9. O. V. Mazurin, M. V. Strel’tsina, and T. P. Shvaiko-Shvaikovskaya,Properties of Glasses and Glass-Forming Melts, A reference book, Vol. 4, Part 2 [in Russian], Nauka, Leningrad (1981).

    Google Scholar 

  10. G. H. Miller and D. White, “Composition-density relationships in ternary glass systems,”Glass Technol.,3(6), 72–78 (1977).

    Google Scholar 

  11. A. I. Rabukhin, “Correlation of structural modifications in glasses with phase diagrams,” in:Publ. of D. I. Mendeleev Russian Chemical Engineering University, Issue 92 [in Russian], Moscow (1976), pp. 24–28.

  12. N. A. Toropov, V. P. Barzakovskii, V. V. Lapin, et al.,Phase Diagrams of Silicate Systems, A Reference Book, Vol. 3, Termary systems [in Russian], Nauka, Leningrad (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. D. I. Mendeleev Russian Chemical Engineering University, Moscow, Russia

    A. I. Rabukhin

Authors
  1. A. I. Rabukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Steklo i Keramika, No. 5, pp. 8–11, May, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rabukhin, A.I. Structural interpretation on the concentration dependence of molar volume in ternary aluminosilicate glasses containing oxides of the first and second groups of the periodic system. Glass Ceram 57, 154–157 (2000). https://doi.org/10.1007/BF02681263

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02681263

Keywords

Search

Navigation