Abstract
The polarization of the fluorescence of radicals formed in laser-induced photodissociation of some disulfides in the gas phase is measured. Experimental data obtained in the study are interpreted within the free recoil model. It is shown that polarization experiments carried out to investigate photodecay in vapors allow researchers to uniquely the intramolecular direction of the dipole moments of transitions with absorption and emission.
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Institute of Molecular and Atomic Physics of the National Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 54–59, January–February, 1999.
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Blokhin, A.P., Gelin, M.F., Kalosha, I.I. et al. Polarized fluorescence of radicals in photodissociation of disulfides in the gas phase. J Appl Spectrosc 66, 55–61 (1999). https://doi.org/10.1007/BF02679219
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DOI: https://doi.org/10.1007/BF02679219