Skip to main content
Log in

Electrochemical synthesis of titanium diboride in the dispersed state from halide melts

  • Theory, Production Technology, and Properties of Powders and Fibers
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Abstract

A study is made of the electrolytic deposition of titanium boride powders from halide melts. The conditions required for the deposition of different phases are determined. On the whole, the synthesis process is controlled by interrelated factors: electrolyte composition, current density, and the temperature and duration of the electrolysis operation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Pat. 1415423 Gr. Britain. Publ. 31.10.73.

  2. Pat. 3697390 USA. Publ. 10.10.72.

  3. Pat. 3880729 USA. Publ. 29.04.75.

  4. Pat. 2132251 France. Publ. 03.03.79.

  5. Pat. 3775271 USA. Publ. 27.11.73.

  6. Pat. 989807 Gr. Britain. Publ. 15.02.62.

  7. V. I. Shapoval, V. V. Malyshev, I. A. Novoselova, and Kh. B. Kushkov, “Current problems of high-temperature electrochemical synthesis in ionic melts,”Usp. Khim.,64, No. 2, 133–141 (1995).

    CAS  Google Scholar 

  8. M. Makyta, K. Matiasavsky, and V. Taranenko, “Mechanism of the cathode process in the electrochecial synthesis of TiB2 in molten salts,”J. Electrochem. Acta,34, No. 6, 861–866 (1989).

    Article  CAS  Google Scholar 

  9. I. V. Zarutskii, V. V. Malyshev, and V. I. Shapoval, “High-temperature electrochemical synthesis of titanium diboride in halide melts,”Zhurn. Prikl. Khim.,70, No. 9, 1475–1482 (1997).

    Google Scholar 

  10. V. I. Shapoval, I. V. Zarutskii, and V. V. Malyshev, “Mechanism of the formation and discharge of electrochemically active particles during the synthesis of titanium diboride in a chloride-fluoride melt.”Élektrokhimiya,34, No. 10, 1107–1113 (1998).

    Google Scholar 

Download references

Authors

Additional information

Deceased.

Institute of General and Inorganic Chemistry, Ukraine National Academy of Sciences, Kiev. Translated from Poroshkovaya Metallurgiya, Nos. 11–12(410), pp. 27–30, November–December, 1999.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shapoval, V.I., Malyshev, V.V. Electrochemical synthesis of titanium diboride in the dispersed state from halide melts. Powder Metall Met Ceram 38, 556–559 (1999). https://doi.org/10.1007/BF02676186

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02676186

Keywords

Navigation