Skip to main content
SpringerLink
Log in

Dependence of the ice-forming activity of dioxinaphthalenes on the structure of the hydrate shell of a crystal

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

Using the1N NMR method of frozen suspensions, we studied the structure of hydrate shells in powders of dioxinaphthalenes (DON). We show that for the 1.5-DON isomer, which has a high ice-forming activity, on a DON/ice interface a thinner (in comparison with the nonactive 2,6- and 2,7-DON isomers) layer of water is formed which is bound with the surface. Moreover, in frozen, 1,5-DON suspensions a great quantity of ice is present, which has an extremely high mobility of water molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Fukuta, J. Atmos. Sci.,23, 191 (1966).

    Article  ADS  Google Scholar 

  2. B. J. Mason, The Physics of Clouds, Oxford (1957).

  3. E. Trinch and R. E. Apfel, J. Chem. Phys.,69, 4245 (1978).

    Article  ADS  Google Scholar 

  4. J. Teixeira and J. Leblond, J. Phys. Lett.,39, L83 (1978).

    Article  Google Scholar 

  5. K. A. Anjell, In: Water and Water Solutions at a Temperature Below 0°C (ed. F. Franks) [Russian translation], Kiev (1985).

  6. A. N. Fletcher, J. Appl. Meteorol.,11, 988 (1972).

    Article  ADS  Google Scholar 

  7. N. H. Fletcher, J. Atm. Sci.,26, 1266 (1969).

    Article  ADS  Google Scholar 

  8. N. O. Plaude and A. D. Solov’ev, Organic Ice-forming Substances [in Russian] (1972).

  9. A. Dennis, Changing Weather by Seeding the Clouds [in Russian], Moscow (1983).

  10. J. Tabony, Progress in NMR Spectroscopy,14, 1 (1980).

    Article  Google Scholar 

  11. I. V. Yazykina, V. I. Kvlividze, and A. V. Krasnushkina, Kolloidn. Zh.,49, 1188 (1987).

    Google Scholar 

  12. B. Z. Gorbunov, L. S. Lazareva, A. Z. Gogolev, and É. A. Zhugichev, Kolloidn. Zh.,51, 1062 (1989).

    Google Scholar 

  13. V. V. Turov, R. Leboda, V. I. Bogillo, and J. Skubishewska-Zieba, Langmuir,11, 931 (1995).

    Article  Google Scholar 

  14. V. V. Turov, K. V. Pogorelyi, and T. N. Burushkina, React. Kinet. Catal. Lett.,50, 279 (1993).

    Article  Google Scholar 

  15. V. V. Mank and N. I. Lebovka, Spectroscopy of Nuclear Magnetic Resonance of Water in Heterogeneous Systems [in Russian], Kiev (1988).

  16. V. P. Glushko (Ed.), Thermodynamic Properties of Individual Subatances, Reference Book [in Russian], Moscow (1978).

  17. V. V. Turov, V. I. Zarko, and A. A. Chuiko, Zh. Fiz. Khim.,69, 677 (1995).

    Google Scholar 

  18. V. M. Gun’ko, V. I. Zarko, V. V. Turov, E. F. Voronin, V. A. Tischenko, and A. A. Chuiko, Langmuir,11, 2115 (1995).

    Article  Google Scholar 

  19. V. V. Turov, R. Leboda, V. I. Bogillo, and J. Skubishewska-Zieba, Langmuir,13, 1237 (1997).

    Article  Google Scholar 

  20. V. V. Turov, React. Kinet. Catal. Lett.,50, 243 (1993).

    Article  Google Scholar 

  21. V. V. Turov, V. I. Bogillo, and A. A. Chuiko, Ukr. Khim. Zh.,59, 580, (1993).

    Google Scholar 

  22. V. V. Turov, V. I. Bogillo, and R. Leboda, Extended Abstracts of Eurofillers’95, Sept. 11–14, 1995, Mulhouse, France (1995), pp. 131–134.

Download references

Author information

Authors and Affiliations

  1. Institute of the Surface Chemistry, National Academy of Sciences of Ukraine, 31 Nauka Ave., 252042, Kiev, Ukraine

    V. V. Turov

  2. T. G. Shevchenko Kiev University, Ukraine

    A. V. Turov & A. V. Arkharov

Authors
  1. V. V. Turov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Turov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Arkharov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 4, pp. 557–561, July–August, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Turov, V.V., Turov, A.V. & Arkharov, A.V. Dependence of the ice-forming activity of dioxinaphthalenes on the structure of the hydrate shell of a crystal. J Appl Spectrosc 65, 578–582 (1998). https://doi.org/10.1007/BF02675651

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02675651

Key words

Search

Navigation