Abstract
Based on the measured spectra of the action of the process of cis-trans-NH(ND)-isomerization of 5-cyano-2,2,8,8,12,13,17, 18-octamethylisobacteriochlorin (H2-COMiBCh) and its deuteroderivative (D2-COMiBCh) in polycrystalline matrices of n-octane and r hexale at 4.2 K, it is established that the character of embedding of COMiBCh in the matrices of n-alkanes has a substantial effect on the barrier of dark rearrangement and the rate of photoinduced NH(ND)-rearrangement, while deuteration of the center of a molecule shifts the dynamic equilibrium toward a trans-form in photoexcitation.
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Reported at the VIIIth International Conference on Spectroscopy of Porphyrins and Their Analogs, Minsk, September 22–26, 1998.
Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70, F. Skorina, Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 4, pp. 555–559, July–August, 1999
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Arabei, S.M., Solov'ev, K.N. Spectra of the action of photoinduced NH(ND)-rearrangement of cyanosubstituted isobacteriochlorin. J Appl Spectrosc 66, 622–626 (1999). https://doi.org/10.1007/BF02675398
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DOI: https://doi.org/10.1007/BF02675398