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Effect of finely dispersed platinum on the structure of luminescence spectra of the adsorbates of magnesium phthalocyanine on silicon dioxide

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Abstract

The luminescence and excitation spectra and kinetic characteristics of the luminescence of the adsorbates of magnesium phthalocyanine (MgPhc) on SiO2 and the effect on them of surface hydration and finely dispersed platinum are studied. It is found that a structure that improves hydration of the adsorbent surface appears on the platinized surface in the luminescence and excitation spectra. It is assumed that the spectral structure is due to the complexes of MgPhc formed with water molecules, the hydroxyl cover of the surface, and the surface centers of SiO2 modified by a Pt-catalyst.

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References

  1. V. I. Korotkov, L. L. Basov, and V. E. Kholmogorov,Dokl. Akad. Nauk SSSR,209, 392–395 (1973).

    Google Scholar 

  2. S. O. Stepanova and V. I. Korotkov,Khim. Vys. Énerg.,30, No. 3, 196–200 (1996).

    Google Scholar 

  3. V. L. Rapoport and N. N. Zhadin,Dokl. Akad. Nauk SSSR,212, No. 6, 1155 (1973).

    Google Scholar 

  4. V. M. Agranovich and M. D. Galanin,Transfer of the Energy of Electron Excitation in Condensed Media [in Russian], Moscow (1978).

  5. D. D. Beck and J. M. White,J. Phys. Chem.,88, 2764–2772 (1984).

    Article  Google Scholar 

  6. A. V. Kiselev and V. I. Lygin,Infrared Spectra of Surface Compounds [in Russian], Moscow (1972).

  7. M. M. Konoplya and Yu. I. Gorlov,Teor. Éksp. Khim.,16, No. 5, 653–659 (1980).

    Google Scholar 

  8. A. N. Sidorov and A. G. Vinogradskii,Opt. Spektrosk.,44, 1113 (1978).

    Google Scholar 

  9. A. A. Chuiko and Yu. I. Gorlov,Chemistry of the Silica Surface: The Structure of the Surface, Active Centers, and the Mechanisms of Sorption [in Russian], Kiev (1992).

  10. V. G. Golovatyi, R. N. Bondarenko, and É. N. Karol',Teor. Éksp. Khim.,11, No. 3, 349–355 (1975).

    Google Scholar 

  11. A. V. Karyakin and A. V. Shablya,Opt. Spektrosk.,5, Issue 6, 655–662 (1958).

    Google Scholar 

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Authors and Affiliations

  1. Scientific-Research Institute of Physics, St. Petersburg State University, 1, Ul'yanovskaya Str., Petrodvorets, 198904, St. Petersburg, Russia

    R. R. Bagautdinov, S. O. Stepanova & V. I. Korotkov

  2. Moscow State University, Russia

    B. N. Korvatovskii

  3. Institute of Analytical Instrument Manufacture, Russian Academy of Sciences, St. Petersburg, Russia

    V. V. Akulinichev

Authors
  1. R. R. Bagautdinov
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  2. S. O. Stepanova
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  3. V. I. Korotkov
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  4. B. N. Korvatovskii
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  5. V. V. Akulinichev
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Additional information

Reported at the VIIIth International Conference on Spectroscopy of Porphyrins and Their Analogs, Minsk, September 22–26, 1998.

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 4, pp. 552–555, July–August, 1999.

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Bagautdinov, R.R., Stepanova, S.O., Korotkov, V.I. et al. Effect of finely dispersed platinum on the structure of luminescence spectra of the adsorbates of magnesium phthalocyanine on silicon dioxide. J Appl Spectrosc 66, 617–621 (1999). https://doi.org/10.1007/BF02675397

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  • DOI: https://doi.org/10.1007/BF02675397

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