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Inductive-resonant triplet-triplet annihilation in solid solutions of erythrosine

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Abstract

Experimental investigations of annihilation-induced delayed fluorescence and phosphorescence of frozen ethylene glycol solutions activated by erythrosine were carried out. It is found that the kinetics of the annihilation-induced delayed fluorescence is nonexponential in the initial stage, and approaches an exponential decay at later stages with the lifetime equal to half the triplet-state lifetime. It is shown that experimental data agree well with the theory proposed to describe triplet-triplet annihilation by an inductive-resonant mechanism in solid solutions of complex organic molecules.

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References

  1. S. Parker, Photoluminescence of Solutions [Russian translation], Moscow (1972).

  2. L. M. Bolot’ko, A. V. Dorokhin, and A. A. Sukhodola, Doklady Akad. Nauk BSSR,31, 619 (1987).

    Google Scholar 

  3. G. A. Ketsle, A. V. Levshin, Yu. D. Lantukh, and S. M. Letuta, in: Abstracts of the All-Union Meeting on Molecular Luminescence, Karaganda (1989), p. 185.

  4. R. E. Kellog, J. Chem. Phys.,41, 3046 (1964).

    Article  Google Scholar 

  5. I. M. Gulis, E. A. Ermilov, and S. A. Sakharuk, Zh. Prikl. Spektrosk.,64, 342 (1997).

    Google Scholar 

  6. G. R. Fleming, A. W. E. Knight, J. M. Morris, et al., J. Am. Chem. Soc.,99, 4306 (1977).

    Article  Google Scholar 

  7. S. L. Murov, I. Carmichael, and G. L. Hug, Handbook of Photochemistry, USA, p. 420 (1993).

  8. A. V. Buettner, J. Phys. Chem.,68, 3253 (1964).

    Article  Google Scholar 

  9. N. A. Efremov, S. G. Kulikov, R. I. Personov, and Yu. V. Romanovskii, Fiz. Tverd. Tela,31, 103 (1989).

    Google Scholar 

  10. M. M. Rikenglaz and I. M. Rozman, Opt. Spektrosk.,36, 106 (1974).

    Google Scholar 

  11. P. P. Feofilov, Polarized Luminescence of Atoms, Molecules, and Crystals [in Russian], Moscow (1959).

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Belarusian State University, 4, F. Skorina Ave., Minsk, 2200050, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 5, pp. 629–632, September–October, 1997.

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Ermilov, E.A., Markovskii, O.L. & Gulis, I.M. Inductive-resonant triplet-triplet annihilation in solid solutions of erythrosine. J Appl Spectrosc 64, 642–645 (1997). https://doi.org/10.1007/BF02675325

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  • DOI: https://doi.org/10.1007/BF02675325

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