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Intermolecular interactions in acetonitrile in a liquid and in a low-temperature argon matrix

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Abstract

IR spectra of acetonitrile embedded in an argon matrix and in a liquid are recorded. IR spectra of specimens obtained with different concentrations of acetonitrile in argon are analyzed. The spectral region of C≡N vibrations of 2200–2300 cm−1 with bands of monomers and possible associates is investigated. Overlap with the band of a hot transition on the low-frequency side is responsible for the pronounced asymmetry of the band ν(C≡N).

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Authors
  1. A. V. Sechkarev
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  2. Yu. A. Fadeev
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  3. I. D. Reva
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St. Petersburg State Institute of Precision Mechanics and Optics (Technical University), 14, Sablinskaya Str., St. Petersburg, 197101, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 5, pp. 627–631, September–October, 1999.

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Sechkarev, A.V., Fadeev, Y.A. & Reva, I.D. Intermolecular interactions in acetonitrile in a liquid and in a low-temperature argon matrix. J Appl Spectrosc 66, 708–714 (1999). https://doi.org/10.1007/BF02675219

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  • DOI: https://doi.org/10.1007/BF02675219

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