Abstract
Profound knowledge of experimental techniques and a large circle of friends around the world made Dr. O. Kubaschewski a leader in data assessment for high-temperature thermochemistry. He was a master of the use of data in graphical form, which served him better than highly-sophisticated programs. Considerable insight into the level of accuracy in the original studies gave Dr. Kubaschewski an unusual ability to foresee and evaluate the data without compromising the measured values. He understood how to use thermodynamic rules to optimize experimental data. New data are constantly being accumulated and the values recommended by Dr. Kubaschewski require changes, but his approach will always be invaluable.
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Cited References
M. Berthelot,Thermochemie. Donnees et Lois Numeriques, Gauthier-Villars etfils, Paris (1897).
F. Dolezalek,Z. Phys. Chem., 64(6), 727–747 (1908).
R.F. Bichowsky, “Thermochemistry: Heats of Formation under Constant Pressure (Heats of Solution, Heats of Transition),”International Critical Tables, Vol. 5, E.W. Washburn, Ed., McGraw-Hill Book Co., New York, 169–213 (1929).
C.G. Maier and K.K. Kelley,J. Am. Chem. Soc., 54,(8), 3243–3246 (1932).
K.K. Kelley, “Contribution to the Data on Theoretical Metallurgy, VII. Thermochemical Data and Free Energy Calculation for Sulfur, Sulfides and Sulfates,”Bull. Bur. Mines, No. 406(1937).
F. Weibke and O. Kubaschewski,Thermochemie der Legierungen, Springer-Verlag, Berlin (1943).
O. Redlich and A.T. Kister,Ind. Eng. Chem.,40, 345 (1948).
F.D. Richardson and J.H.E. Jeffes,J. Iron Steel Inst.,160 (11), 261–270 (1948).
J.H. Hildebrand and R.L. Scott,The Solubility of Non-Electmlytes, Reinhold, N. Y. (1950).
O. Kubaschewski and J.A. Catterall,Thermochemical Data of Alloys, Pergamon, London ( 1956).
S. Andersson, B. Collen, U. Kuylenstierna, and H. Magneli,Acta Chem.Scand.,11, (10), 1641–1652 (1957).
S.N. Ruddlesden and P. Popper,Acta Crystallogr, 11, 54–55 (1958).
D.L. Martin,Proc. R. Soc. (London) A, 254(1279), 433–454 (1960).
O. Kubaschewski and B.E. Hopkins,Oxidation of Metals and Alloys, 2nded., Butterworth,London (1962).
L.S. Darken,Trans. AIME, 239(1), 80–89 (1967).
G.T. Furukawa, W.G. Saba, and M.L. Reilly, “Critical Analysis of the Heat Capacity Data of the Literature and Evaluation of Thermo-dynamic Properties of Copper, Silver and Gold from 0 to 300 K,”National Stand Ref. Data Series, 18, National Bureau of Standards (NSRDS-NBS),49pp(1968).
I. Barin and O. Knacke,Thermochemical Properties of Inorganic Substances, Spnnger-Verlag, Berlin (1973).
C.W. Bale and A.D. Pelton,Metall. Trans., 5(11), 2323–2337 (1974).
L.V. Gurvich, I.V. Veits, V.A. Medvedev, G.A. Khachkuruzov, V.S. Yungman, G.A. Bergman, et al., “Thermodinamicheskie Svoistva Individual ’nikh Veschestv (Thermodynamic Properties of Individual Substances)”; V.P. Glushko, Gen. Ed., Vol. 1, parts 1 and 2 (1978); Vol 2, parts 1 and2(1979);Vol.3, parts 1 and2(1981); Vol.4, parts 1 and2(1982); Izdatel’stvo“Nauka,” Moscow (1978/1982).
O. Kubaschewski and C.B. Alcock,Metallurgical Thermo-chemistry, 5th ed., Pergamon Press, Oxford (1979).
C.B. Alcock and V.P. Itkin, “Description of the Excess Thermo-dynamic Properties by the Chebyshev Polynomials,”Computer Modelling of Phase Diagrams, L.H. Bennett, Ed., Proc. Symp. TMS, Toronto, Canada, October 1985, Metallurgical Society, Warrendale, PA (1986).
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Alcock, C.B., Itkin, V.P. The art and science of thermochemical data assessment. JPE 14, 409–412 (1993). https://doi.org/10.1007/BF02671957
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DOI: https://doi.org/10.1007/BF02671957