Abstract
The aim of this study was to investigate the influences of heat transfer, thermal gradient, solidification rate, and the addition of up to 1 pct Ni and 1 pct Cr on the solidification and macrosegregation of high-carbon (0.8 pct), low-alloy steel. Sixteen 13.6-kg laboratory ingots were horizontally and unidirectionally cast in a static moll, fitted on one face with a water-cooled copper chill to simulate a continuous casting mold. Thermocouples, placed in the chill and the mold, were used to calculate heat flux, thermal gradient, and solidification rate. The ingots were examined with respect to macro- and microstructures, distribution of phases, dendrite arm spacing, and solute element distribution. The extent of macrosegregation of carbon and sulfur was determined by wet chemical analysis of drillings, and a TANDEM VAN DE GRAAFF accelerator was used for A1, Si, P, V, S, C, Mn, Ni, and Cu. The extent of macrosegregation of these elements was correlated with heat transfer and thermodynamic distribution coefficient data.
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J.J. Moore:Proc. CANMET Conference on Effects of Inclusions and Residual Elements on Fabrication and Service Behaviour of Steels, Mar, 1985. Ottawa, J.D. Bryce and C.S. Champion, eds., CANMET, Ottawa, ON, pp. 73–100.
D.J. Hurtuk: Ph.D. Thesis, Case Western Reserve University, Cleveland, OH, Jan. 1981.
J.J. Moore:I & SM, 1980, vol. 7, pp. 8–16.
N.A. Shah, J.H. Broadhurst, and J.J. Moore:Microstructural Sci., 1983, vol. 12, pp. 550–71.
N.A. Shah and J.J. Moore:Steelmaking Proc., 1983, vol. 66, pp. 247–60.
J.J. Moore and N.A. Shah:CIM Annual Conf. Symp. on Continuous Casting of Steel, Vancouver, BC, 1985, CIM, Montreal, PQ, Canada, pp. 5–32.
Y. Ito, N. Masumitsu, and K. Matsubara:Trans. ISIJ, 1981, vol. 21, p. 477.
T. Takada, I. Bessko, and T. Ito:Trans. ISIJ, 1978, vol. 18, p. 564.
M.C. Flemings:Solidification Processing, McGraw-Hill, Inc., New York, NY, 1974.
A. Suzuki, T. Suzuki, Y. Nagaoka, and Y. Iwata:On the Spacing of Secondary Arms in Plain Steel with Different Carbon Contents, Hendry Brutcher Translation No. 7804, 1969.
A. Suzuki, T. Suzuki, Y. Nagaoka, and Y. Iwata:Nippon Kingaku Gakkai Shuko, 1967, p. 32.
G.J. Henzel and J. Keverian:AFS Trans., 1960, vol. 68, p. 373.
I.M. MacKenzie and A. Donald:JISI, 1962, vol. 200, p. 41.
V. Davis:Br. Foundryman, 1980, vol. 73, pp. 331–34.
A.D. Akimenio and A.A. Skvortsox:Izv. Vyssh. Uchebn. Zaved. Chern. Metall., 1958, vol. 12, pp. 45–50.
K. Ushijim:Tetsu-to-Hagané, 1961, vol. 47 (3), pp. 390–91.
J.J. Gautier, Y. Morillon, and J. Dumont-Fillon:JISI, 1970, vol. 208 (12), pp. 1053–59.
S. Watanabe, K. Harada, N. Fujito, Y. Tamuro, and K. Noro:Tessu-to-Hagané, 1972, vol. 58 (11), pp. 393–94.
H. Krainer and B. Tarmann:Stahl Eisen, 1949, vol. 69, p. 83.
H. Krainer and B. Tarmann:Engineer, 1955, vol. 200, p. 389.
A. Grill, K. Sorimachi, and J.K. Brimacombe:Metall. Trans. B, 1977, vol. 8B, pp. 489–505.
O. Richmond and R.M. Tin:J. Mech. Phys. Solid, 1971, vol. 19, pp. 273–84.
E. Homes, J.W. Rutter, and W.C. Winegard:Can. J. Phys., 1957, vol. 35, p. 1223.
J.S. Kirkaldy and W.V. Youdelis:TMS-AIME, 1958, vol. 212, p. 833.
W. Youdelis:Physical Chemistry of Process Metallurgy, Part 2, Interscience, New York, NY, 1961.
W.V. Youdelis:Can. J. Phys., 1964, vol. 42, p. 2238.
W.V. Youdelis,The Solidification of Metals, ISI, London, 1968, no. 11, p. 112.
H. Sandberg:Scand. J. Metall., 1973, vol. 2, p. 233.
C. Bodsworth and H.B. Bell:Physical Chemistry of Iron and Steel Manufacture, 2nd ed., Longmans, London, 1972, p. 486,
J.F. Elliott, H. Glliser, and V. Ramakrishna,Thermo-Chemistry of Steel Making, Addison-Wesley, Reading, MA, 1963, vol. II.
C. Bodsworth and H.B. Bell,Physical Chemistry of Iron and Steel Manufacture, 2nd ed., Longmans, London, 1972, pp. 448–505.
T. Fujii, D.R. Poirier, and M.C. Flemings:Metall. Trans. B, 1979, vol. 10B, pp. 331–39.
M.C. Flemings, R. Mehrabian, and G.E. Nereo:TMS-AIME, 1968, vol. 242, pp. 41–49.
M.C. Flemings and G.E. Nereo:TMS-AIME, 1968, vol. 242, pp. 50–55.
R. Mehrabian, M. Keane, and M.C. Fleming:Metall. Trans., 1970, vol. 1, pp. 1209–20.
R. Mehrabian and M.C. Flemings:Solidification, ASM, Cleveland, OH, 1971, p. 311.
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Shah, N.A., Moore, J.J. Effect of thermal conditions and alloying constituents (Ni, Cr) on macrosegregation in continuously cast high-carbon (0.8 Pct), low-alloy steel. Metall Trans B 20, 893–910 (1989). https://doi.org/10.1007/BF02670195
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DOI: https://doi.org/10.1007/BF02670195