Skip to main content
Log in

Dissolution of solid copper cylinder in molten tin-lead alloys under dynamic conditions

  • Published:
Metallurgical Transactions B Aims and scope Submit manuscript

Abstract

The dissolution of a copper cylinder in molten tin-lead alloys was studied at 673 K under static and dynamic conditions in the peripheral velocity range 1.9 to 75.4 cm per second using an immersion method. The dissolution rate of copper increased with increasing tin concentration and peripheral velocity. The solution rate constant increased with peripheral velocity and with diffusion coefficient of copper in the melt. The constant decreased with kinematic viscosity of the melt and diameter of the specimen. The dissolution of copper in molten tin-lead alloys was mixed control. Flow of the melt under forced convection was turbulent flow with Taylor vortices. Natural convection occurred in dissolution of stationary copper in tin rich alloys due to hydrodynamic instability from density differences in the melt.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W.G. Bader:Weld. J., 1969, vol. 48, pp. 551-S-557-S.

    Google Scholar 

  2. T. Ishida:Trans. Jpn. Weld. Soc., 1972, vol. 3, pp. 1–6.

    Google Scholar 

  3. H. Fidos and H. Schreiner:Z. Metallk., 1970, vol. 61, pp. 273–78.

    CAS  Google Scholar 

  4. H. Yamaguchi and Y. Hisamatsu:Trans. Iron Steel Inst. Jpn., 1979, vol. 19, pp. 649–58.

    Google Scholar 

  5. Y. Kim and R. D. Pehlke:Metall. Trans., 1974, vol. 5, pp. 2527–32.

    Article  CAS  Google Scholar 

  6. J. R. Weeks and D.H. Gurinsky:Liquid Metals and Solidification, ASM, Metals Park, OH, 1958, pp. 106–61.

    Google Scholar 

  7. T. Ishida:Trans. Jpn. lnst. Met., 1973, vol. 14, pp. 37–44.

    Google Scholar 

  8. Y. Shoji, S. Uchida, and T. Ariga:Trans. Jpn. lnst. Met., 1980, vol. 21, pp. 383–89.

    CAS  Google Scholar 

  9. M. Hansen:Constitution of Binary Alloys, McGraw-Hill Book Co., New York, NY, 1958, pp. 633–38.

    Google Scholar 

  10. M. Hansen:Constitution of Binary Alloys, McGraw-Hill Book Co., New York, NY, 1958, pp. 609–12.

    Google Scholar 

  11. E. A. Moelwyn-Hughes:The Kinetics of Reaction in Solution, 2nd ed., Clarendon Press, Oxford, 1947, pp. 374–77.

    Google Scholar 

  12. Y. Shoji, S. Uchida, and T. Ariga:Weld. J., 1981, vol. 60, pp. 19-S-24-S.

    Google Scholar 

  13. W. Sutherland:Phil. Mag., 1905, vol. 9, pp. 781–85.

    CAS  Google Scholar 

  14. C.J. Smithells:Metals Reference Book, 3rd ed., Butterworths, London, 1962, vol. I, p. 136.

    Google Scholar 

  15. H.R. Thresh and A.F. Crawley:Metall. Trans., 1970, vol. 1, pp. 1531–35.

    Article  CAS  Google Scholar 

  16. C.H. Ma and R.A. Swalin:Acta Met., 1960, vol. 8, pp. 383–95.

    Article  Google Scholar 

  17. J.W. Gorman and G. W. Preckshot:Trans. TMS-AIME, 1958, vol. 212, pp. 367–73.

    CAS  Google Scholar 

  18. H. Schlichting:Boundary-Layer Theory, 6th ed., McGraw-Hill Book Co., New York, NY, 1968, pp. 24–43.

    Google Scholar 

  19. H.R. Thresh, A.F. Crawley, and D.W.G. White:Trans. TMS-AIME, 1968, vol. 242, pp. 819–22.

    CAS  Google Scholar 

  20. M. Eisenberg, C. W. Tobias, and C. R. Wilke:Chem. Eng. Prog. Symp. Ser., 1955, vol. 51, no. 16, pp. 1–16.

    Google Scholar 

  21. M. Kosaka and S. Minowa:Tetsu-to-Hagane, 1966, vol. 52, pp. 1748–62.

    CAS  Google Scholar 

  22. H. Schilichting:Boundary-Layer Theory, 6th ed., McGraw-Hill Book Co., New York, NY, 1968, pp. 500–03.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

YOSHIFUSA SHOJI, formerly Graduate Student, Tokai University, Tokyo

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shoji, Y., Uchida, S. & Ariga, T. Dissolution of solid copper cylinder in molten tin-lead alloys under dynamic conditions. Metall Trans B 13, 439–445 (1982). https://doi.org/10.1007/BF02667760

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02667760

Keywords

Navigation