Skip to main content
Log in

Hydrogen-Induced subcritical crack growth of a 12 Cr-1 Mo ferritic stainless steel

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

Subcritical crack growth and tensile ductility measurements have been made on a 12 Cr-1 Mo ferritic stainless steel at cathodic potentials in a 1 N H2SO4 solution at 25 °C. The tensile ductility was found to be a minimum at −600 mV (SCE) and both the subcritical crack growth behavior and tensile ductility were similar for material in the tempered (760 °C/2.5 h) or tempered-plus-segregated (540 °C/240 h) condition. A rising-load crack growth threshold of 20 MPa √m was measured and a rising-load fracture toughness of 110 MPa √m was determined from extrapolation of the stage III crack growth curve. A K-independent stage II was observed and a stage II crack growth rate of about 1 × 10−5 mm/s was measured. The fracture mode was a mixture of intergranular and quasi-cleavage for both heat treatments and for subcritical and tensile fracture tests. Impact fracture properties were independent of heat treatment and grain boundary composition with the fracture mode predominantly transgranular. The difference in the fracture mode for hydrogen-induced crack growth and dynamic crack growth was explained by a difference in the relationship between their stress profiles and the maximum grain boundary segregation distribution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. H. Jones, S. M. Bruemmer, M. T. Thomas, and D. R. Baer:Metall. Trans. A, 1981, vol. 12A, pp. 1621–29.

    Google Scholar 

  2. J. Kameda and C. J. McMahon, Jr.:Metall. Trans. A, 1981, vol. 12A, pp. 31–37.

    Google Scholar 

  3. C. L. Briant:Scripta Met., 1981, vol. 15, pp. 1013–18.

    Article  CAS  Google Scholar 

  4. R. H. Jones and M. T. Thomas: inProceedings of the Topical Conference on “Ferritic Alloys for Use in Nuclear Energy Technologies”, Snowbird, UT, June 1983, J. W. Davis and D. J. Michel, eds., TMS-AIME, Warrendale, PA, pp. 395–404.

    Google Scholar 

  5. J. M. Hyzak and W. M. Garrison: Alloy Development for Irradiation Performance Semi-Annual Progress Report for Period Ending March 31, 1982, DOE/ER-0045/8, pp. 401–13.

  6. E. D. Hondros and M. P. Seah:International Metals Reviews, 1977, vol. 222, pp. 262–301.

    Google Scholar 

  7. L. E. Davis, N.C. MacDonald, P. W. Palmberg, G. F. Riach, and R. E. Weber:Handbook of Auger Electron Spectroscopy, Physical Electronics Industries, Eden Prairie, MN, 1976.

    Google Scholar 

  8. M. P. Seah and W. A. Dench:Surface and Interface Analysis, 1979, vol. 1, p. 2.

    Article  CAS  Google Scholar 

  9. H. J. Grabke, E. M. pctersen, and S. R. Srinivasan:Surf. Sci., 1977, vol. 67, pp. 501–16.

    Article  CAS  Google Scholar 

  10. R. H. Jones, S. M. Bruemmer, M. T. Thomas, and D. R. Baer:Scripta Met., 1982, vol. 16, pp. 615–20.

    Article  CAS  Google Scholar 

  11. M. Pourbaix:Atlas of Electrochemical Equilibria in Aqueous Solutions, Pergamon Press, Oxford, England, 1966.

    Google Scholar 

  12. R. H. Jones, S. M. Bruemmer, M. T. Thomas, and D. R. Baer:Metall. Trans. A, 1982, vol. 13A, pp. 241–49.

    CAS  Google Scholar 

  13. S. M. Bruemmer, R. H. Jones, M. T. Thomas, and D. R. Baer:Metall. Trans. A, 1983, vol. 14A, pp. 223–32.

    Google Scholar 

  14. R. H. Jones, S. M. Bruemmer, M. T. Thomas, and D. R. Baer:Metall. Trans. A, 1983, vol. 14A, pp. 1729–36.

    CAS  Google Scholar 

  15. B. J. Berkowitz and R. D. Kane:Corrosion, 1980, vol. 36, pp. 24–29.

    CAS  Google Scholar 

  16. R. H. Jones, M. T. Thomas, and D. R. Baer:Metall. Trans. A, 1985, vol. 16A,pp. 123–31.

    CAS  Google Scholar 

  17. R.A. Oriani and P. H. Josephic:Acta Metall., 1974, vol. 22, pp. 1065–74.

    Article  CAS  Google Scholar 

  18. W. W. Gerberich, J. Garry, and J. F. Lessar:Effect of Hydrogen on Behavior of Materials, A.W. Thompson and I. M. Bernstein, eds., TMS-AIME, Warrendale, PA, 1975, pp. 70–82.

    Google Scholar 

  19. R.A. Oriani and P. H. Josephic:Acta Metall., 1977, vol. 25, pp. 979–88.

    Article  CAS  Google Scholar 

  20. W. G. Clark and J.D. Landes:Stress Corrosion—New Approaches, ASTM STP 610, American Society for Testing Materials, Philadelphia, PA, 1976, pp. 108–27.

    Google Scholar 

  21. K. Sieradzki:Scripta Met., 1981, vol. 15, pp. 171–76.

    Article  CAS  Google Scholar 

  22. R. H. Jones and W. G. Wolfer: in Proceedings of the Third Fusion Reactor Materials Meeting, Albuquerque, NM, August 1983,Journal of Nucl. Mater., 1984, vol. 122-123, pp. 379–90.

    Article  Google Scholar 

  23. G. R. Odette, G. E. Lucas, R. Maiti, and J. W. Sheckherd: in Proceedings of the Third Fusion Reactor Materials Meeting, Albuquerque, NM, August 1983,Journal of Nucl. Mater., 1984, vol. 122-123, pp. 442–47.

    Article  Google Scholar 

  24. R. O. Ritchie, J. F. Knott, and J. R. Rice:J. Mech. Phys. Solids, 1973, vol. 21, p. 395.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jones, R.H. Hydrogen-Induced subcritical crack growth of a 12 Cr-1 Mo ferritic stainless steel. Metall Trans A 17, 1229–1240 (1986). https://doi.org/10.1007/BF02665323

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02665323

Keywords

Navigation