Skip to main content
Log in

Deformation and stored energy of polycrystalline bismuth

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

Stress-strain curves of polycrystalline bismuth deformed in compression were obtained at 78, 193, 243, 273, 298 and 353 K at strain rates of 2.2 × 10-4, 2.2 × 10-3 and 2.2 × 10-2 s-1. The strain rate sensitivity was measured by strain rate change tests. Activation volumes and activation enthalpies of deformation were determined. The stored energy of cold work was measured by liquid metal solution calorimetry.

The flow stress shows a large strain rate dependence except at 78 K; its strain rate sensitivity goes through a maximum in the range of 243 to 273 K. The interpretation of the activation volume and activation enthalpy suggests that the deformation mechanism changes between 193 and 243 K and between 298 and 353 K. The stored energy of cold work increases at first linearly with strain and at a strain of approximately 0.5 levels off to a saturation value of about 420 J .g-atom-1. The stored energy and the ratio of the stored to the expended energy are unusually large. Some conclusions are drawn regard-ing the deformation mechanism of bismuth.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. J. Gough and H. L. Cox:J. Inst. Metals, 1932, vol. 48, pp. 227–47.

    Google Scholar 

  2. R. E. Slonaker, M. Smutz, H. Jensen, and E. H. Oison:J. Less-Common Metals, 1965, vol. 8, pp. 327–38.

    Article  CAS  Google Scholar 

  3. T. l. Lange:Soviet Research in New Semiconductor Materials, D. N. Nasledov and N. A. Goryunova (Translated), eds., pp. 85-87, Consultants Bureau, 1965.

  4. W. F. Berg:Nature, 1934, vol. 134, p. 143.

    CAS  Google Scholar 

  5. A. A. Bochvar, V. A. Abramova, and M. G. Khan:Izv. Akad. Nauk SSSR,Met. Gorn. Delo, 1964, no. 1, pp. 92-94.

  6. M. Georgieff and E. Schmid:Z. Phys., 1926, vol. 36, pp. 759–74.

    Article  CAS  Google Scholar 

  7. V. P. Shishokin:Izv. Akad. Nauk SSSR, 1937, no. 6, p. 134.

  8. M. B. Bever, D. L. Holt, and A. L. Titchener:Prog. in Mater. Sci., vol. 17, Pergamon Press, 1973.

  9. H. J. Gough:Proc. ASTM, 1933, vol. 33, pp. 3–114.

    Google Scholar 

  10. G. A. Hare and H. D. Melon:Metallurgia, 1961, vol. 63, pp. 208–09.

    Google Scholar 

  11. B. W. Howlett, J. S. LI. Leach, L. B. Ticknor, and M. B. Bever:Rev. Sci. Instrum., 1962, vol. 33, pp. 619–24.

    Article  CAS  Google Scholar 

  12. P. Chaudhari, P. Beardmore, and M. B. Bever:Phys. Chem. Glasses, 1966, vol. 7, pp. 157–58.

    CAS  Google Scholar 

  13. G.C. Das and M. B. Bever:Met. Trans., 1973, vol. 4, pp. 1457–61.

    CAS  Google Scholar 

  14. R. Hultgren, R. L. Orr, P. D. Anderson, and K. K. Kelley:Selected Values of the Thermodynamic Properties of Metals and Alloys, John Wiley, New York, 1963.

    Google Scholar 

  15. G. Y. Chin:Work Hardening in Tension and Fatigue, pp. 45–66, AIME, 1977.

  16. R. W. Armstrong, I. Codd, R. M. Douthwaite, and N. J. Petch:Phil. Mag., 1962, vol. 7, pp. 45–58.

    Article  CAS  Google Scholar 

  17. Z. S. Basinski and J. W. Christian:Aust. J. Phys., 1960, vol. 13, pp. 299–308.

    CAS  Google Scholar 

  18. T. L. Altshuler and J.W. Christian:Phil. Trans. Roy. Soc. (London), Ser.A, 1967, vol. 261, pp. 253–87.

    Article  CAS  Google Scholar 

  19. J. W. Christian and B. C. Masters:Proc. Roy. Soc, 1964, vol. A281, pp.223–39.

    Google Scholar 

  20. F. Guiu:Phys. Status Solidi, 1967, vol. 19, pp. 339–51.

    Article  CAS  Google Scholar 

  21. D. Hull:Acta Met., 1961, vol. 9, pp. 191–204.

    Article  CAS  Google Scholar 

  22. P. J. Worthington:Scr. Met., 1968, vol. 2, pp. 701–03.

    Article  Google Scholar 

  23. R. W. Armstrong and P. J. Worthington:Metallurgical Effects at High Strain Rates, pp. 401–14, Plenum Press, New York, 1973.

    Google Scholar 

  24. G. Y. Chin:Deformation of Ceramic Materials, pp. 25–59, Plenum Press, New York, 1974.

    Google Scholar 

  25. R. W. Armstrong and J. D.Campbell:Third Intern. Conference on the Strength of Metals and Alloys, the Microstructure and Design of Alloys, pp. 529–33, Institute of Metals (London), 1973.

    Google Scholar 

  26. H. Conrad:The Relation Between the Structure and Mechanical Properties of Metals, pp. 476–516, H.M.S.O., London, 1963.

    Google Scholar 

  27. D. J. Bailey and W. F. Flanagan:Phil. Mag., 1969, vol. 19, pp. 1093–1103.

    Article  Google Scholar 

  28. V. I. Khotkevich, E. F. Chaiovskii, and V. V. Zashkvara:Dokl. Akad. Nauk SSSR, 1954, vol.96,pp.483–86.

    CAS  Google Scholar 

  29. V. I. Khotkevich and G. A. Sirenko:Ukr. Fiz. Zh., 1969, vol. 14, pp. 1558–60.

    CAS  Google Scholar 

  30. A. S. Appleton and M. B. Bever:Trans. TMS-AIME, 1963, vol. 227, pp. 365–71.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Das, G.C., Bever, M.B. Deformation and stored energy of polycrystalline bismuth. Metall Trans A 9, 1875–1881 (1978). https://doi.org/10.1007/BF02663422

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02663422

Keywords

Navigation