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The germanium selenide/polymer bilevel photoresist system — A review

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Abstract

The germanium selenide/polymer bilevel photoresist system is reviewed covering the literature up to mid 1984. The review is oriented towards the prospects of germanium selenide as a high resolution photoresist for VLSI production and covers the preparation of the lithographic product and its processing. These processes include sensitization, exposure, fixing and development. The mechanism of silver photodoping in germanium selenide is also discussed. After considering the outstanding problems, it is concluded that the photoresist system has reached a sufficient degree of maturity for implementation in a production environment.

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References

  1. J.C. Phillips, J. Non-Cryst. Solids36, 1157 (1980).

    Article  Google Scholar 

  2. D.E. Aspnes, J.C. Phillips, K.L. Tai, and P.M. Bridenbaugh, Phys. Rev. B 23, 816 (1981).

    Article  CAS  Google Scholar 

  3. C.H. Chen, J.C. Phillips, and K.L. Tai, Solid State Commun. 38, 657 (1981).

    Article  CAS  Google Scholar 

  4. R.J. Nemanich, G.A.N. Connell, T.M. Hayes, and R.A. Street, Phys. Rev. B.18, 6900 (1978).

    Article  CAS  Google Scholar 

  5. H.J. Trodahl and L. Vina, Phys. Rev. B27, 6498 (1983).

    Article  CAS  Google Scholar 

  6. P. Boolchand, J. Grothaus, and J.C. Phillips, Solid State Commun.45, 183 (1983).

    Article  CAS  Google Scholar 

  7. M. Janai, 9th Int. Conf. Amorph. Liq. Semicond. (1981).

  8. D.A. Doane and A. Heller, ECS Proc. 82-9, 1 (1982).

    Google Scholar 

  9. K.L. Tai, E. Ong, and R.G. Vadimsky, Proc. Symp. Inorg. Resists (ECS-82-9), 9 (1982).

  10. R.G. Vadimsky, K.L. Tai, and E. Ong., Proc. Symp. Inorg. Resists (ECS-82-9), 37 (1982).

  11. E. Ong, K. Tai, E. Reichmanis, and C.W. Wilkins, Interface 81, Kodak Microel. Seminar, 91 (1981

  12. M.T. Kostyshin, E.V. Mikhailovskaya, and P.F. Romanenko, Sov. Phys.: Sol. State8, 451 (1966).

    Google Scholar 

  13. M.T. Kostyshin, E.P. Krasnozhenov, V.A. Makeev, P.F. Romanenko, and G.A. Sobolev, Sov. J. Quant. Electron.5, 1103 (1976).

    Article  Google Scholar 

  14. R.W. Hallman and G.W. Kurtz, US Patent 3 707 372, (1972).

    Google Scholar 

  15. I. Shimizu, H. Sakuma, H. Kokado, and E. Inoue, Photogr. Sci. Eng.l6, 291 (1972).

    Google Scholar 

  16. T. Shlrakawa, I. Shimizu, H. Kokado, and E. Inoue, Photogr. Sci. Eng.19, 139 (1975).

    Google Scholar 

  17. H. Kokado, I. Shimizu, and E. Inoue, J. Non-Cryst. Solids20, 131 (1976).

    Article  CAS  Google Scholar 

  18. M. Janai and P.S. Rudman, Photogr. Sci. Eng.20, 234 (1976).

    CAS  Google Scholar 

  19. S. Rajagopalan, B. Singh, P.K. Bhat, D.K. Pandya, and K.L. Chopra, J. Appl. Phys.50, 489 (1979).

    Article  CAS  Google Scholar 

  20. K.L. Tai, E. Ong, R.G. Vadimsky, C.T. Kemmerer, and P.M. Bridenbaugh, Proc. Symp. Inorg. Resists (ECS-82-9), 49 (1982).

  21. H. Nagai, A. Yoshikawa, Y. Toyoshima, O. Ochi, and Y. Mizushima, Appl. Phys. Lett.28, 145 (1976).

    Article  CAS  Google Scholar 

  22. A. Yoshikawa, O. Ochi, H. Nagai, and Y. Mizushima, Appl. Phys. Lett.29, 677 (1976).

    Article  CAS  Google Scholar 

  23. A. Yoshikawa, H. Nagai, O. Ochi, K. Nakano, and Y. Mizushima, US Patent 4 127 414, (1978).

    Google Scholar 

  24. A. Yoshikawa, O. Ochi, H. Nagai, and Y. Mizushima, Appl. Phys. Lett.31., 161 (1977).

    Article  Google Scholar 

  25. K.L. Tai, W.R. Sinclair, R.G. Vadimsky, and J.A. Moran, J. Vac. Sci. Techn.16, 1977 (1979).

    Article  CAS  Google Scholar 

  26. V.E. Lamberti, S.M. Vincent, C.T. Kemmerer, and R.G. Vadimsky, Proc. Symp. Inorg. Resists (ECS-82-9), 191 (1982).

  27. K.L. Tai, R.G. Vadimsky, C.T. Kemmerer, J.S. Wagner, and V.E. Lamberti, J. Vac. Sci. Techn.17, 1169 (1980).

    Article  CAS  Google Scholar 

  28. A. Yoshikawa, S. Hirota, O. Ochi, A. Takeida, and Y. Mizushima, Jap. J. Appl. Phys. Lett.20, 81 (1981).

    Article  Google Scholar 

  29. A. Yoshikawa, O. Ochi, and Y. Mizushima, Appl. Phys. Lett.36, 107 (1980).

    Article  CAS  Google Scholar 

  30. P.G. Huggett, K. Frick, and H.W. Lehmann, Appl. Phys. Lett.42, 592 (1983).

    Article  CAS  Google Scholar 

  31. B. Singh, S. Rajagopalan, P.K. Bhat, D.K. Pandya, and K.L. Chopra, Sol. State Commun.29, 167 (1979).

    Article  CAS  Google Scholar 

  32. K. Balasubramanyam and A.L. Ruoff, J. Vac. Sci. Techn.19, 1374 (1981).

    Article  CAS  Google Scholar 

  33. K.S. Harshavardhan, S. Rajagopalan, L.K. Malhotra, and K.L. Chopra, J. Appl. Phys.54, 1048 (1983).

    Article  CAS  Google Scholar 

  34. K. Balasubramanyam, L.J. Chen, A.L. Ruoff, and E.D. Wolf, J. Appl. Phys.53, 5975 (1982).

    Article  CAS  Google Scholar 

  35. A. Heller, K.L. Tai, and R.G. Vadimsky, Europ. Patent Appl. 80102402. 7, (1980).

  36. A. Wagner, D. Barr, T. Venkatesan, W.S. Crane, and V.E. Lamberti, J. Vac. Sci. Techn.19, 1363 (1981).

    Article  CAS  Google Scholar 

  37. P.G. Huggett and H.W. Lehmann, Microcircuit Engineering’83, 363 (1983).

    Google Scholar 

  38. B. Singh, S.P. Beaumont, P.G. Bower, and C.D.W. Wilkinson, Appl. Phys. Lett.41, 1002 (1982).

    Article  CAS  Google Scholar 

  39. N. Funakoshi, S. Zembutsu, and T. Kasai, Japn. J. Appl. Phys. Lett.20, 649 (1981).

    Article  Google Scholar 

  40. Y. Mizushima, A. Yoshikawa, Y. Utsugi, and S. Zembutsu, Unpublished, Proc. Symp. Inorg. Res. (ECS-82-9), (1982).

  41. I. Lauks, G.C. Chern, and K.Y. Toh, Proc. Symp. Inorg. Resists (ECS-82-9) 93 (1982).

  42. G.C. Chern and I. Lauks, J. Appl. Phys. 53, 6979 (1982).

    Article  CAS  Google Scholar 

  43. G.C. Chern and I. Lauks, J. Appl. Phys.54, 2701 (1983).

    Article  CAS  Google Scholar 

  44. G.C. Chern, I. Lauks, and A.R. McGhie, J. Appl. Phys.54, 4596 (1983).

    Article  CAS  Google Scholar 

  45. T. Venkatesan, J. Vac. Sci. Techn.19, 1368 (1981).

    Article  CAS  Google Scholar 

  46. T. Venkatesan and B. Wilkens, Proc. SPIE-Int. Soc. Opt. Eng.333, 163 (1982).

    CAS  Google Scholar 

  47. T. Venkatesan and B. Wilkens, Appl. Phys. Lett.41, 839 (1982).

    Article  CAS  Google Scholar 

  48. B. Singh, S. Rajagopalan, and K.L. Chopra, J. Appl. Phys.51., 1768 (1980).

    Article  Google Scholar 

  49. B. Singh and K.L. Chopra, Phys. Stat. Sol. A (Letter)68, 5 (1981).

    Article  Google Scholar 

  50. R.M. Lum, W.R. Sinclair, R.P. Jones, and V.E. Lamberti, Proc. Symp. Inorg. Resists (ECS-82-9), 223 (1982).

  51. S.M. Vincent and T.Y. Kometani, Proc. Symp. Inorg. Resists (ECS-82-9), 169 (1982).

  52. P.M. Bridenbaugh, G.P. Espinosa, J.E. Griffiths, J.C. Phillips, and J.P. Remeika, Phys. Rev. B20, 4140 (1979).

    Article  CAS  Google Scholar 

  53. J.E. Griffiths and W.R. Sinclair, Appl. Phys. Lett.39, 551 (1981).

    Article  CAS  Google Scholar 

  54. J.E. Griffiths, Proc. Symp. Inorg. Resists (ECS-82-9), 203 (1982).

  55. K. Balasubramanyam, L. Karapiperis, C.A. Lee and A.L. Ruoff, J. Vac. Sci. Techn.19, 18 (1981).

    Article  CAS  Google Scholar 

  56. N. Funakoshi, S. Fujimori, S. Zembutsu, and T. Kasai, Japn. J. Appl. Phys. Lett.21, 40 (1982).

    Article  Google Scholar 

  57. C.H. Chen and K.L. Tai, Appl. Phys. Lett.37, 1075 (1980).

    Article  CAS  Google Scholar 

  58. R.G. Vadimsky and K.L. Tai, ECS Ect. Abstr. 80-2, 824 (1980).

    Google Scholar 

  59. K.L. Tai, Eur. Pat. 0042 109, (1981).

    Google Scholar 

  60. A. Heller and R.G. Vadimsky, US Pat. 4,343,887, (1982).

    Google Scholar 

  61. C.H. Tzinis, C.H. Chen, and C.T. Kemmerer, Proc. Symp. Inorg. Resists (ECS-82-9), 157 (1982).

  62. J.I. Masters, G.M. Goldberg, J.M. Lavine, US Pat. 4,316,946, (1982).

    Google Scholar 

  63. A. Das, US Pat. 4,371,608, (1983).

    Google Scholar 

  64. A. Wagner and D. Barr, Proc. Symp. Inorg. Resists (ECS-82-9), 281 (1982).

  65. T. Venkatesan, B. Wilkens, and S. Vincent, J. Appl. Phys.53, 6453 (1982).

    Article  CAS  Google Scholar 

  66. S. Zembutsu, Appl. Phys. Lett.39, 969 (1981).

    Article  CAS  Google Scholar 

  67. T. Ueno and A. Odajima, Japn. J. Appl. Phys.21, 230 (1982).

    Article  CAS  Google Scholar 

  68. K.L. Tai, L.F. Johnson, D.W. Morphy, and M.S.T. Chung, ECS Ext. Abstr. 79-1, 244 (1979).

    Google Scholar 

  69. E. Ong, K.L. Tai, R.G. Vadimsky, and C.T. Kemmerer, Proc. Symp. Inorg. Resists (ECS-82-9), 71 (1982).

  70. NTT Corp., Japn. Kokai Tokkyo Koho JP 57,104,930, (1982).

  71. B. Singh, S.P. Beaumont, P.G. Bower, and C.D. Wilkinson, Appl. Phys. Lett.41, 889 (1982).

    Article  CAS  Google Scholar 

  72. K.J. Polasko, Y.W. Yau, and R.F.W. Pease, Opt. Eng.22, 195 (1983).

    CAS  Google Scholar 

  73. H. Sakuma, I. Shimizu, H. Kokado, and E. Inoue, Proc. Third Conf. Sol. State Devices (Tokyo) (1972).

  74. S.A. Lis and J.M. Lavine, Appl. Phys. Lett.42, 675 (1983).

    Article  CAS  Google Scholar 

  75. H. Fritsche, J. Phys. Soc. Jpn. Suppl. A,49, 39 (1980).

    Google Scholar 

  76. K.L. Tai, R.G. Vadimsky, and V.E. Lamberti, ECS Ext. Abstr. 80-2, 826 (1980).

    Google Scholar 

  77. K.L. Tai, Jpn. J. Appl. Phys. Lett.21., 300 (1982).

    Article  Google Scholar 

  78. N. Funakoshi and S. Zembutsu, Jpn. J. Appl. Phys. Lett.21., 300 (1982).

    Article  Google Scholar 

  79. M. Marcus, A. Wagner, and T. Hanley, Proc. Symp. Inorg. Resists (ECS-82-9), 295 (1982).

  80. S.A. Lis, J.M. Lavine, J.I. Masters, and G.M. Goldberg, Proc. ECS Symp. (ECS-83-1), 275 (1983).

  81. A. Yoshikawa, O. Ochi, T. Hisaki, and Y. Mizushima, US Pat. 4,320,191, (1982).

    Google Scholar 

  82. A. Yoshikawa, O. Ochi, A. Takeda, and Y. Mizushima, J. Electrochem. Soc.129, 1074 (1982).

    Article  CAS  Google Scholar 

  83. K. Graff and H. Pieper, Proc. Symp. Semiconductor Silicon (ECS 1981), 331 (1981).

  84. Y. Mizushima, A. Takeda, A. Yoshikawa, and O. Ochi, Fr. Demande FR 2, 463, 509, (1981).

    Google Scholar 

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Huggett, P.G., Lehmann, H.W. The germanium selenide/polymer bilevel photoresist system — A review. J. Electron. Mater. 14, 205–230 (1985). https://doi.org/10.1007/BF02661219

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