Abstract
The growth of GaInAsP lattice matched to GaAs using tertiary-butylphosphine and ethyldimethylindium to replace the more conventional phosphine and trimethylindium is described. The quaternary compound lattice matched to GaAs has received far less attention than related compositions that lattice match InP. Using the new sources, most of the growth problems experienced by previous workers have been avoided. Uniform compositions have been grown reproducibly without evidence of gas-phase, adduct-forming reactions. Bothn- andp-type films have been grown. Heteroepitaxy of high quality GalnAsP layers on Ge has also been achieved, and microstructural results are presented.
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T. Mizutani, M. Yoshida, A. Usui, H. Watanabe, T. Tuasa and I. Hayashi, Jpn. J. Appl. Phys.19, L113 (1980).
J. P. Hirtz, J. P. Duchemin, P. Hirtz, B. de Cremoux, T. Pearsall and M. Bonnet, Electron. Lett.16, 275 (1980).
J. P. Duchemin, J. P. Hirtz, M. Razeghi, M. Bonnet and S. D. Hersee, J. Cryst. Growth55, 64 (1981).
J. L. Benchimol, M. Quillec and S. Slempkes, J. Cryst. Growth64, 96 (1983).
R. H. Moss and P. C. Spurdens, J. Cryst. Growth68, 96 (1984).
S. Sugou, A. Kameyama, Y. Miyamoto, K. Furuya and Y. Suematsu, Jpn. J. Appl. Phys.23, 1182 (1984).
A. Mircea, R. Mellet, B. Rose, D. Robein, H. Thibierge, G. Leroux, P. Daste, S. Godefroy, P. Ossart and A-M. Pougnet, J. Electron. Mater.15, 205 (1986).
A. W. Nelson, S. Cole, S. Wong, M. J. Harlow, W. J. Devlin, D. Wake, P. M. Rodgers and M. J. Robertson, J. Cryst. Growth77, 579 (1986).
W. T. Tsang, E. F. Schubert, T. H. Chiu, J. E. Cunningham, E. G. Burkhardt, J. A. Ditzenberger and E. Agyekum, Appl. Phys. Lett.51, 761 (1987).
C. Caneau, H. J. Yoo, R. Bhat, M. Koza and J. R. Hayes, J. Cryst. Growth102, 491 (1990).
M. J. Ludowise, W. T. Dietze and C. R. Lewis, Inst. Phys. Conf. Ser. No. 65, 93 (1983).
T. Iwamoto, K. Mori, M. Mizuta and H. Kukimoto, Jpn. J. Appl. Phys.22, L191 (1983).
EDMIn obtained from Morton International, Special Chem- icals Group, Danvers, MA 01923.
TBP obtained from American Cyanamid, Wayne, NJ 07470.
K. L. Fry, C. P. Kuo, C. A. Larsen, R. M. Cohen, G. B. Stringfellow and A. Melas, J. Electron. Mater.15, 91 (1986).
J. Knauf, D. Schmitz, G. Strauch, H. Jurgensen, M. Heyen and A. Melas, J. Cryst. Growth93, 34 (1988).
P. R. Sharps, M. L. Timmons and T. S. Colpitts, Appl. Phys. Lett.58, 2006 (1991).
P. K. York, K. J. Beernink, J. Kim, J. J. Coleman, G. E. Fernandez and C. M. Wayman, Appl. Phys. Lett.54, 2476 (1989).
G. B. Stringfellow, Organometallic Vapor-Phase Epitaxy: Theory and Practice (Academic Press, San Diego, CA, 1989), pp. 38, 39.
Y. Takeda, S. Araki, M. Takemi, S. Noda and A. Sasaki, Jpn. J. Appl. Phys.29, L1040 (1990).
GaAs substrates supplied by Bertram Laboratory, Somer- ville, NJ 08876.
Ge substrates supplied by Laser Diode Laboratory, Inc., Me- tuchen, NJ 08840.
G. E. Stillman, L. W. Cook, N. Tabatabaie, G. E. Bulman and V. Robbins, IEEE Trans. Elect. Dev.ED-30, 364 (1983).
N. Amir, D. Fekete and Y. Nemirovsky, J. Appl. Phys.68, 871 (1990).
M. J. Ludowise, J. Appl. Phys.58, R31 (1985).
A. Mircea, R. Mellet, B. Rose, D. Robein, H. Thibierge, G. Leroux, P. Daste, S. Godefroy, P. Ossart and A-M. Pougnet, J. Electron. Mater.15, 205 (1986).
D. M. Szmyd, P. Porro, A. Majerfeld and S. Lagomarsino, J. Appl. Phys. 68, 2367 (1990).
A. W. Nelson, S. Cole, S. Wong, M. J. Harlow, W. J. Devlin, D. Wake, P. M. Rodgers and M. J. Robertson, J. Cryst. Growth77, 579 (1986).
Measurements were made on samples similar in structure to those shown in.
S. W. Choi, K. J. Bachmann, J. B. Posthill and M. L. Tim- mons, accepted in J. Electrochem. Soc.
A. G. Norman and G. R. Booker, J. Appl. Phys.57, 4715 (1985).
F. Glas, M. M. J. Treacy, M. Quillec and H. Launois, J. Phys. Paris43, C5 (1982).
S. Mahajan, B. V. Dutt, H. Temkin, R. J. Cava and W. A. Bonner, J. Cryst. Growth68, 589 (1984).
O. Ueda, S. Isozumi and S. Komiya, Jpn. J. Appl. Phys.23, L241 (1984).
B. deCremoux, P. Hirtz and J. Ricciardi, Inst. Phys. Conf. Series56, 115 (1981).
G. B. Stringfellow, J. Electron. Mater.11, 903 (1982).
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Sharps, P.R., Posthill, J.B. & Timmons, M.L. Growth of Ga x In1−x As y P1−y using ethyldimethylindium andt-butylphophine. J. Electron. Mater. 21, 317–321 (1992). https://doi.org/10.1007/BF02660460
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DOI: https://doi.org/10.1007/BF02660460