Skip to main content
Log in

Embrittlement of a 5 Pct Nickel high strength steel by impurities and their effects on hydrogen-induced cracking

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

Temper embrittlement induced by isothermal aging at 480°C (753 K) in a commercially produced heat of HY 130 steel is shown by Auger electron spectroscopy to be due mainly to intergranular segregation of Si, with additional contributions by P, N, and Sn. Studies of rates of crack growth in gaseous hydrogen at controlled temperature and pressure in specimens aged various amounts showed that, as the impurity concentration increased, the stress intensity for crack growth Kth dropped precipitously, the cracking mode changed from cleavage to intergranular, and the crack growth rate atK > K th increased. Hydrogen-induced crack growth occurred in a step-wise, rather than continuous, fashion. The impurity-plus-hydrogen effect is discussed in terms of a model adapted from an earlier theory of Oriani.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. U. Q. Cabral, A. Hache, and A. Constant:C. R. Acad. Sci., 1965, vol. 260 T, p. 6887.

    Google Scholar 

  2. K. Yoshino and C. J. McMahon, Jr.:Met. Trans., 1974, vol. 5, p. 363.

    CAS  Google Scholar 

  3. J. R. Low, Jr., D. F. Stein, A. M. Turkalo, and R. P. Laforce:Trans. TMS-AIME, 1968, vol. 242, p. 14.

    CAS  Google Scholar 

  4. B. J. Schulz and C. J. McMahon, Jr.:Temper Embrittlement of Alloy Steels, vol. 499, ASTM STP, p. 104, 1972.

  5. S. R. Novak and S. T. Rolfe:J. Mater., 1969, vol. 4, p. 701.

    Google Scholar 

  6. J. F. Knott:Fundamentals of Fracture Mechanics, p. 131, Butterworths, London,1973.

    Google Scholar 

  7. J. M. Capus:J. Iron Steel Inst., 1962, vol. 200, p. 922.

    CAS  Google Scholar 

  8. Handbook of Auger Electron Spectroscopy, 2nd ed., Physical Electronics Ind. Inc., 1976.

  9. M. Guttmann:Surface Sci., 1975, vol. 53, p. 213.

    Article  CAS  Google Scholar 

  10. C. J. McMahon, Jr., C. L. Briant, and S. K. Banerji:Proceedings, Fourth International Conference on Fracture, Waterloo, Canada, June 1977, in press.

  11. A. R. Troiano:Trans. ASM, 1960, vol. 52, p. 54.

    Google Scholar 

  12. R. A. Oriani:Bunsen-Gesellschaft Phys. Chetn., 1972, vol. 76, p. 848.

    CAS  Google Scholar 

  13. J. R. Rice and M. A. Johnson:Inelastic Behavior of Solids, M. F. Kanninen,et al, eds., p. 641, McGraw-Hill, New York, 1970.

    Google Scholar 

  14. J. R. Rice:J. Appl. Mech., 1968, vol. 35, p. 379.

    Google Scholar 

  15. J. C. M. Li, R. A. Oriani, and L. W. Darken:Z. Phys. Chem., 1966, vol. 49, p. 271.

    CAS  Google Scholar 

  16. R. A. Orianiand, P.H. Josephic:Acta Met., 1974, vol. 27, p. 1065.

    Article  Google Scholar 

  17. G. Lapasset, J. P. Laurent, M. Aucouturier, and P. Lacombe:L ’Hydrogene dan lesMetaux, Editions Science et Industrie, Paris, 1972.

    Google Scholar 

  18. H. H. Johnson, J. G. Morlet, and A. R. Troiano:Trans. TMS-AIME, 1958, vol. 212, pp. 528–36.

    CAS  Google Scholar 

  19. C.F. Barthand, E.A. Steigerwald:Met. Trans., 1970, vol. 1, pp. 3451–55.

    Google Scholar 

  20. Comment of Key Reader.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Formerly Post Doctoral Fellow, Department of Metallurgy and Materials Science, University of Pennsylvania

Formerly on the Research Staff, LRSM, University of Pennsylvania

Rights and permissions

Reprints and permissions

About this article

Cite this article

Briant, C., Feng, H.C. & McMahon, C.J. Embrittlement of a 5 Pct Nickel high strength steel by impurities and their effects on hydrogen-induced cracking. Metall Trans A 9, 625–633 (1978). https://doi.org/10.1007/BF02659919

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02659919

Keywords

Navigation