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Reaction of trimethyliod osilane with alkyl aryl ethers

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

alkyl aryl ethers react with trimethyliodosilane at 120–135° in the absence of a catalyst to give the corresponding trimethylaroxysilanes and alkyl halide. An increase in the length of the alkyl radical or the insertion of a substituent in the o-position of the aromatic ring hinders the reaction.

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Literature Cited

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Deceased.

Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2355–2356, October, 1976.

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Voronkov, M.G., Dubinskaya, É.I., Pavlov, S.F. et al. Reaction of trimethyliod osilane with alkyl aryl ethers. Russ Chem Bull 25, 2198–2199 (1976). https://doi.org/10.1007/BF02659549

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  • DOI: https://doi.org/10.1007/BF02659549

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