Conclusions
alkyl aryl ethers react with trimethyliodosilane at 120–135° in the absence of a catalyst to give the corresponding trimethylaroxysilanes and alkyl halide. An increase in the length of the alkyl radical or the insertion of a substituent in the o-position of the aromatic ring hinders the reaction.
Literature Cited
M. Kumada and H. Hattori, J. Inst. Polytechnics, Ser. C, 3 (1952).
R. Schwarz and W. Kuchen, Chem. Ber.,89, 169 (1956).
M. G. Voronkov, S. F. Pavlov, and É. I. Dubinskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 657 (1975).
M. G. Voronkov, S. F. Pavlov, and É. I. Dubinskaya, Dokl. Akad. Nauk SSSR,227, 607 (1976).
M. G. Voronkov, V. E. Puzanova, S. F. Pavlov and É. I. Dubinskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 448 (1975).
M. G. Voronkov and Yu. I. Khudobin, Zh. Obsch. Khim.,26, 584 (1956).
M. G. Voronkov and Yu. I. Khudobin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 713 (1956).
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Deceased.
Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2355–2356, October, 1976.
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Voronkov, M.G., Dubinskaya, É.I., Pavlov, S.F. et al. Reaction of trimethyliod osilane with alkyl aryl ethers. Russ Chem Bull 25, 2198–2199 (1976). https://doi.org/10.1007/BF02659549
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DOI: https://doi.org/10.1007/BF02659549