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Relative reactivity of arylethylenes in reaction with fluor obromocarbene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The relative rate constants for the addition of fluorobromocarbene to a number of arylethylenes were determined.

  2. 2.

    The reaction proceeds by the electrophilic addition mechanism via a weakly polar transition state.

  3. 3.

    In the arylethylene series the selectivity of fluorobromocarbene is close to that of the dichloro- and difluorocarbenes.

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Authors
  1. V. S. Aksenov
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  2. G. A. Terent'eva
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  3. N. I. Ilyasova
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Additional information

Institute of Petroleum Chemistry, Siberian Branch of the Academy of Sciences of the USSR, Tomsk. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2353–2354, October, 1976.

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Aksenov, V.S., Terent'eva, G.A. & Ilyasova, N.I. Relative reactivity of arylethylenes in reaction with fluor obromocarbene. Russ Chem Bull 25, 2196–2197 (1976). https://doi.org/10.1007/BF02659548

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  • DOI: https://doi.org/10.1007/BF02659548

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