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Phase composition of skeletal ruthenium catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An x-ray and thermogravimetric study was made of the phase composition of a skeletal ruthenium that was obtained by the decomposition of a Ru−Al alloy (30% Ru) with caustic alkalis. It was found that, besides highly dispersed metallic ruthenium, the catalyst contains bayerite.

  2. 2.

    Skeletal ruthenium catalyst when heated to 600° decomposes in stages due to dehydration of the bayerite.

  3. 3.

    The same as in the case of the Ni−Al alloy, complex aluminum salts are formed during the leaching of the aluminum from a Ru−Al alloy, which then decompose with the formation of aluminum trihydroxide.

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Literature Cited

  1. D. V. Sokol'skii, T. K. Kabiev, and Zh. Kairbekov, Collection of Chemical Papers, [in Russian], Vol. 3, Nauka, Alma-Ata (1973), p. 521.

    Google Scholar 

  2. Kh. I. Yankovskii, Author's Abstract of Candidate's Dissertation, Moscow (1974).

  3. E. I. Klabunovskii, N. P. Sokolova, A. A. Vedenyapin, N. D. Zubareva, Yu. M. Talanov, V. P. Polyakova, and N. B. Gorina, Izv. Akad. Nauk SSSR, Ser. Khim., 2361 (1972).

  4. A. A. Vedenyapin, E. I. Klabunovskii, N. P. Sokolova, N. D. Zubareva, G. Kh. Areshidze, E. V. Leonova, A. K. Ivanov, E. I. Savitskii, V. P. Polyakova, and N. B. Gorina, Proceedings of All-Union Convention on Noble Metal Alloys and Their Substitutes [in Russian], Moscow (1975).

  5. Structure and Properties of Adsorbents and Catalysts [in Russian], Mir (1973), p. 192.

  6. Natl. Bur. Stand., Circular 539,4, 5 (1955).

  7. Z. Csuros, Zs. Dusza, J. Petro, L. Erdey, and F. Paulik, Acta. Chim. Hung.,42, 131 (1964).

    CAS  Google Scholar 

  8. Z. Csuros, J. Petro, V. Kalman, L. Erdey, and F. Paulik, Period. Polytechn. Chem. Eng.,10, 27 (1966).

    CAS  Google Scholar 

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Authors
  1. A. A. Vedenyapin
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  2. N. D. Zubareva
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  3. V. M. Akimov
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  4. E. I. Klabunovskii
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  5. N. G. Giorgadze
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  6. N. E. Barannikova
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Additional information

N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2340–2343, October, 1976.

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Vedenyapin, A.A., Zubareva, N.D., Akimov, V.M. et al. Phase composition of skeletal ruthenium catalyst. Russ Chem Bull 25, 2184–2187 (1976). https://doi.org/10.1007/BF02659544

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  • DOI: https://doi.org/10.1007/BF02659544

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