Conclusions
The tautomeric process in, the trimethylsily derivative of methylnitramine in various different solvents has been investigated using the dynamic nuclear magnetic resonance, (DNMR) method, and it has been shown that the tautomeric transition involves a multicenter cyclic transition state.
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Additional information
N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2320–2325, October, 1976
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Ioffe, S.L., Blyumenfel'd, A.L., Shashkov, A.S. et al. The mechanism of the Si(CH3)3 group migration in the trimethylsilyl derivative of methylnitramine. Russ Chem Bull 25, 2164–2169 (1976). https://doi.org/10.1007/BF02659540
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DOI: https://doi.org/10.1007/BF02659540