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Fluoroindenes

5. Reaction of octafluoroindene with sources of difluorocarbene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of octafluoroindene with hexafluoropropylene oxide at 190–195° yields perfluoro-1,1a,6,-6a-tetrahydrocycloprop[a]indene, while the products at 230° are the perfluoro-1,2- and perfluoro-1,4-dihydronaphthalenes.

  2. 2.

    The reaction of octafluoroindene with either hexafluoropropylene oxide or tetrafluoroethylene at 670° leads to perfluoro-2-methylindene.

  3. 3.

    The pyrolysis of perfluoro-1,1a,6,6a-tetrahydrocycloprop[1]indene at 230° gives chiefly perfluoro-2-methylindene, and octafluoroindene at 670°.

  4. 4.

    The action of nitric acid in HF on perfluoro-2-methylindene gives perfluoro-2-nitro-2-methylindan.

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Literature cited

  1. V. M. Karpov, V. E. Platonov, and G. G. Yakobson, Izv. Akad. Nauk SSSR, Ser. Khim., 375 (1976).

  2. V. M. Karpov, V. E. Platonov, and G. G. Yakobson, Izv. Akad. Nauk SSSR, Ser. Khim., 981 (1976).

  3. O. M. Nefedov and A. A. Ivashenko, Izv. Akad. Nauk SSSR, Ser. Khim., 446 (1968); O. M. Nefedov and A. A. Ivashenko, USSR Patent 279608 (1970); Byull. Izobr., No. 27 (1970); F. Nerdel, G. Blume, and P. Weyerstahl, Tetrahedron Lett., 2867 (1969).

  4. W. E. Parham, H. E. Reiff, and P. Swartzentruber, J. Am. Chem. Soc.,78, 1437 (1956).

    Article  CAS  Google Scholar 

  5. J. M. Birchall, R. Fields, R. N. Haszeldine, and N. T. Kendall, J. Chem. Soc. Perkin Trans.,1, 1773 (1973).

    Article  Google Scholar 

  6. P. Tarrant and E. Stamp, Zh. Vses. Khim. O-va,15, 34 (1970).

    Google Scholar 

  7. P. B. Sergeant, J. Org. Chem.,35, 678 (1970); R. W. Hoffmann, Angew. Chem. Internat. Edit.,10, 529 (1971).

    Article  Google Scholar 

  8. K. V. Dvornikova, V. E. Platonov, L. N. Pushkina, S. V. Sokolov, G. P. Tataurov, and G. G. Yakobson, Zh. Org. Khim.,8, 1042 (1972).

    CAS  Google Scholar 

  9. V. M. Karpov, V. E. Platonov, and G. G. Yakobson, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,4, No. 2, 124 (1974).

    Google Scholar 

  10. V. M. Karpov, V. E. Platonov, and G. G. Yakobson, Zh. Org. Khim.,10, 663 (1974).

    CAS  Google Scholar 

  11. V. I. Slovetskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2215 (1970).

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Authors
  1. V. M. Karpov
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  2. V. E. Platonov
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  3. G. G. Yakobson
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Additional information

See [1] for Communication 4.

See [2] for preliminary communication.

Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR. Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2295–2299, October, 1976.

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Karpov, V.M., Platonov, V.E. & Yakobson, G.G. Fluoroindenes. Russ Chem Bull 25, 2141–2144 (1976). https://doi.org/10.1007/BF02659535

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  • DOI: https://doi.org/10.1007/BF02659535

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