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Application of the chemical ionization method to a mass-spectroscopic study of carbohydrates

1. β-methyl-2,3,4,6-tetra-O-methyl-D-galactopyranoside

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the fragmentation paths in chemical ionization of β-methyl-2,3,4,6-tetra-O-methyl-D-galactopyranoside.

  2. 2.

    The quasimolecular ions of this compound are capable of successive splitting of one, two, and three methanol molecules, the preferred positions for methoxyl elimination being 1, 3, and 4, respectively.

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Authors
  1. A. A. Solov'ev
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  2. E. I. Kadentsev
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  3. O. S. Chizhov
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Additional information

N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2256–2261, October, 1976.

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Solov'ev, A.A., Kadentsev, E.I. & Chizhov, O.S. Application of the chemical ionization method to a mass-spectroscopic study of carbohydrates. Russ Chem Bull 25, 2105–2109 (1976). https://doi.org/10.1007/BF02659526

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  • DOI: https://doi.org/10.1007/BF02659526

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