Skip to main content
Log in

19F,31P, and1H NMR spectra of the bis(trifluoromethyl)aminophosphoranes

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Molecules of the types F2PXYN(CF3)2, F2C2lPY, and {ie2068-1} have been prepared and studied through19F,31P, and1H NMR spectra.

  2. 2.

    It was found that there are certain regularities in the variation of the parameters of the NMR spectra on moving through any one series of these compounds.

  3. 3.

    It has been shown that each of the compounds studied here is the fluoride of five-coordinated phosphorus.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature Cited

  1. H. J. Emeleus and T. Onak, J. Chem. Soc., A, 1291 (1966).

  2. R. Schmutzler, Halogen. Chem.,2, 31 (1967).

    CAS  Google Scholar 

  3. G. I. Drozd, M. A. Sokal'skii, V. V. Sheluehenko, M. A. Landau, and S. Z. Ivin, Zh. Obshch. Khim.,39, 935, 939 (1969).

    CAS  Google Scholar 

  4. G. Mavel, Progr. Nucl. Magn. Reson. Spectrosc.,1, 251 (1967).

    Article  Google Scholar 

  5. J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High-Resolution Nuclear Resonance Spectroscopy, Vol. 2, Pergamon (1966).

  6. V. Mark, C. H. Dungan, M. M. Crutchfield, and J. R. Van Wazer, Top. Phosphorus Chem.,5, 227 (1967).

    CAS  Google Scholar 

  7. G. I. Drozd, Usp. Khim.,39, 3 (1970).

    CAS  Google Scholar 

  8. G. I. Drozd, V. V. Lysenko, and S. Z. Ivin, Advances with the Chemistry of Phosphorganic and Sulfo-organic Compounds [in Russian], Issue 2, Naukova Dumka, Kiev (1970), p. 5.

    Google Scholar 

  9. V. V. Sheluchenko, M. A. Landau, S. S. Dubov, A. A. Neimysheva, and I. L. Knunyants, Dokl. Akad. Nauk SSSR,177, 376 (1967).

    CAS  Google Scholar 

  10. A. Schmutzler and G. S. Reddy, Inorg. Chem.,4, 191 (1965).

    Article  CAS  Google Scholar 

  11. M. A. Landau, V. V. Sheluchenko, G. I. Drozd, S. S. Dubov, and S. Z. Ivin, Zh. Strukt. Khim.,8, 1097 (1967).

    CAS  Google Scholar 

  12. G. I. Drozd, M. A. Sokal'skii, O. G. Strukov, and S. Z. Ivin, Zh. Obshch. Khim.,40, 2396 (1970).

    CAS  Google Scholar 

  13. D. E. Huheey, J. Phys. Chem.,69, 3284 (1965);70, 2086, (1966).

    Article  CAS  Google Scholar 

Download references

Authors

Additional information

Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2210–2217, October, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fokin, A.V., Landau, M.A., Drozd, G.I. et al. 19F,31P, and1H NMR spectra of the bis(trifluoromethyl)aminophosphoranes. Russ Chem Bull 25, 2063–2068 (1976). https://doi.org/10.1007/BF02659517

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02659517

Keywords

Navigation