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Effect of high pressure on hydrogen atom detachent by tert-butoxy radicals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Increasing the pressure increases the rate of H atom detachment in hydrocarbon substitution by tertbutoxy radicals, the increase being the more pronounced the higher the rate constants for the reaction at atmospheric pressure.

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Literature Cited

  1. V. M. Zhulin, B. I. Rubinshtein, and M. Ya. Botnikov, Izv Akad. Nauk SSSR, Ser. Khim., 293 (1975).

  2. C. Walling and J. A. McGuiness, J. Am. Chem. Soc.,91 2053 (1969).

    Article  CAS  Google Scholar 

  3. A. A. Zavitsas and J. D. Blank, J. Am. Chem. Soc,94, 4603 (1972).

    Article  CAS  Google Scholar 

  4. V. M. Zhulin, M. G. Gonikberg and B. N. Zagorbinina, Izv. Akad. Nauk SSSR., Otd. Khim. Nauk, 716 (1962).

  5. B. S. El'yanov and M. G. Gonikberg, Izv. Akad. Nauk SSSR Otd. Khim. Nauk, 934 (1961); Zh. Fiz. Khim.,36, 604 (1962).

    Google Scholar 

  6. B. S. El'yanov and M. G. Gonikberg, Izv. Akad. Nauk SSSR, Ser, Khim., 1044 (1967).

  7. G. A. Russell, J. Am. Chem. Soc.,79, 2977 (1957);80, 4987, 4997, 5002 (1958).

    Article  CAS  Google Scholar 

  8. G. A. Russell, J. Org. Chem.,24, 300 (1959).

    Article  CAS  Google Scholar 

  9. C. Walling and G. Metzger, J. Am. Chem. Soc.,81, 5365 (1959).

    Article  CAS  Google Scholar 

  10. J. H. T. Brook, Trans. Faraday Soc.,53, 327 (1957).

    Article  CAS  Google Scholar 

  11. A. A. Zavitsas and J. A. Pinto, J. Am. Chem. Soc.,94, 7390 (1972).

    Article  CAS  Google Scholar 

  12. V. M. Zhulin Izv. Akad Nauk SSSR, Ser. Khim., 2361 (1971).

  13. V. M. Zhulin, M. Ya. Botnikov and I. Kh. Milyavskaya, Izv. Akad. Nauk SSSR. Ser. Khim., 1131 (1975).

  14. M. Szwarc, Special Publication, No. 16, Chem. Soc. London (1962), p. 96.

  15. V. M. Zhulin, M. Ya. Botnikov, and I. Kh. Milyavskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 488 (1975).

  16. H. Sakurai and A. Hosomi, J. Am. Chem. Soc.,89, 458 (1967).

    Article  CAS  Google Scholar 

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Authors
  1. V. M. Zhulin
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  2. B. I. Rubinstein
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Additional information

N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2201–2204, October, 1976.

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Zhulin, V.M., Rubinstein, B.I. Effect of high pressure on hydrogen atom detachent by tert-butoxy radicals. Russ Chem Bull 25, 2055–2058 (1976). https://doi.org/10.1007/BF02659515

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  • DOI: https://doi.org/10.1007/BF02659515

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