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Catalysis of cis—Trans isomerization by macromolecules containing conjugated bonds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Macromolecules with conjugated bonds can catalyze cis—trans isomerization by increasing the probability of reaction along an adiabatic path.

  2. 2.

    Acceleration coefficients for cis—trans isomerization have been calculated.

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Literature Cited

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Authors
  1. A. A. Berlin
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  2. G. A. Vinogradov
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  3. A. A. Ovchinnikov
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Additional information

Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow. L. Ya. Karpov Physicochemical Institute, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2197–2200, October, 1976.

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Berlin, A.A., Vinogradov, G.A. & Ovchinnikov, A.A. Catalysis of cis—Trans isomerization by macromolecules containing conjugated bonds. Russ Chem Bull 25, 2052–2054 (1976). https://doi.org/10.1007/BF02659514

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  • DOI: https://doi.org/10.1007/BF02659514

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